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Tumbling Cerium Atoms Inside the Fullerene Cage:iCe2C80

 

作者: M. Kanai,   K. Porfyrakis,   A. N. Khlobystov,   H. Shinohara,   T. J. S. Dennis,  

 

期刊: AIP Conference Proceedings  （AIP Available online 1903）
卷期: Volume 685, issue 1  

页码: 41-45

 

ISSN:0094-243X

 

年代: 1903

 

DOI:10.1063/1.1627983

 

出版商: AIP

 

数据来源: AIP

 

摘要:

We report the spectroscopic work of two Ce‐containingincar‐fullerenes,iCeC82andiCe2C80. UV/Vis, IR, Raman, TOF‐MALDI and13C NMR were employed to investigate the structural and electronic information of these two major isomers of Ceincar‐fullerenes. Tumbling motion of two Ce atoms inside the Ih‐C80cage was confirmed and analysed by temperature‐dependant13C NMR. © 2003 American Institute of Physics

 

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