Aggregation of sulfonated poly(p‐phenylene terephthalamide) in dilute solutions
作者:
Evan Y. Chu,
Z. S. Xu,
C. M. Lee,
Cindy K. F. Sek,
Y. Okamoto,
E. M. Pearce,
T. K. Kwei,
期刊:
Journal of Polymer Science Part B: Polymer Physics
(WILEY Available online 1995)
卷期:
Volume 33,
issue 1
页码: 71-75
ISSN:0887-6266
年代: 1995
DOI:10.1002/polb.1995.090330108
出版商: John Wiley&Sons, Inc.
关键词: rigid polymer;sulfonated poly(p‐phenylene terephthalamide);polymer aggregation;solution viscosity
数据来源: WILEY
摘要:
AbstractThe viscosities of dilute solutions of poly(p‐phenylene terephthalamide), PPTS, in dimethylacetamide, water, and their mixtures were determined. The reduced viscosity plot in dimethylacetamide shows a negative slope. When the water content in the mixed solvent in 90% or higher, there is an upswing in the reduced viscosity values at concentrations below 0.1 g/dL. The latter behavior suggests a “polyelectrolyte” effect. However, an association model was found to be able to explain the viscosity behaviors in both solvents. ©1995 John Wiley&Son
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