Chiral Liquid Crystalline Polyacrylates with Side-Chain Fluorescent Mesogens
作者:
E. Chiellini,
J.L. Houben,
D. Wolff,
G. Galli,
期刊:
Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals
(Taylor Available online 2000)
卷期:
Volume 352,
issue 1
页码: 439-447
ISSN:1058-725X
年代: 2000
DOI:10.1080/10587250008023202
出版商: Taylor & Francis Group
关键词: chiral polyacrylate;liquid crystalline polymer;mesophase structure;fluorescent mesogen
数据来源: Taylor
摘要:
Two new classes of chiral side-chain polymers comprising a variously spaced biphenyl unit as both a mesogenic core and a fluorescent chromophore were investigated. The chiral group was either a 2,3- or a 2,2-disubstituted oxirane ring. The structures of the smectic phases (A, B, or E) were investigated by X-ray diffraction. Excimer fluorescence emission was detected at room temperature in the smectic phase.
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