Rheo-Optical Properties of a Thermotropic Liquid Crystalline Polymer
作者:
Mohan Srinivasarao,
RaulO. Garay,
H.Henning Winter,
RichardS. Stein,
期刊:
Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals
(Taylor Available online 1992)
卷期:
Volume 223,
issue 1
页码: 29-39
ISSN:1058-725X
年代: 1992
DOI:10.1080/15421409208048238
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Rheo-optical studies on aligned and unaligned melts of a main chain thermotropic polyester with flexible spacers are discussed in terms of the predictions of the Ericksen-Leslie equations. Experiments show that the material exhibits two different shear-flow regimes depending on the temperature at which the experiments are performed. It is shown, using conoscopy, that the director is flow-aligning at temperatures close to TNIand nonflow-aligning close to a smectic to nematic (TSN) phase transition. The implications of these results are discussed in terms of the change in sign of one of the Leslie viscosity coefficients and interpreted in the framework of the Ericksen-Leslie Theory.
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