A REACTION KINETICS MODEL OF SHALE OIL UPGRADING IN SUPERCRITICAL WATER
作者:
StephenC. Paspek,
MichaelT. Klein,
期刊:
Fuel Science and Technology International
(Taylor Available online 1991)
卷期:
Volume 9,
issue 7
页码: 839-854
ISSN:0884-3759
年代: 1991
DOI:10.1080/08843759108942299
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
A kinetics model of the upgrading of shale oil in supercritical water (SCW) was developed. The model predicts the yields of coke (C)asphalt (A), resid (R), distillate (D) and gas (G), as well as nitrogen (N) removal as a function of batch reaction or plug flow holding time, from the reaction of shale oil in SCW with added catalyst and hydrogen. Mechanistically derived submodels provide the functional dependence of the overall rates of reaction of C, A, R, D and G on process variables. The model can be utilized in two complementary ways. First, it is a quantitative summary of mechanistic insights and hypotheses that suggest further laboratory testing. Second, it can be useful in process engineering calculations.
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