Effect of substrate temperature and heat treatment on the microstructure of diamondlike carbon films
作者:
Sanjay Bhargava,
H. D. Bist,
A. V. Narlikar,
S. B. Samanta,
J. Narayan,
H. B. Tripathi,
期刊:
Journal of Applied Physics
(AIP Available online 1996)
卷期:
Volume 79,
issue 4
页码: 1917-1925
ISSN:0021-8979
年代: 1996
DOI:10.1063/1.361081
出版商: AIP
数据来源: AIP
摘要:
Nonhydrogenated diamondlike carbon films prepared at a substrate temperature (ST) of 100, 300, and 500 °C by the laser ablation of graphite on a single‐crystal silicon substrate have been characterized by scanning tunneling microscopy for the surface structure and Raman spectroscopy for the microstructure. Distorted pentagonal and hexagonal rings are observed on the surface of the film grown at 100 °C while only hexagonal rings are observable for the one grown at 500 °C. The rise in ST is found to increase the surface roughness. To assign the various coexisting carbonaceous species formed at different growth temperatures and to check their thermal stability, heat treatment was performed at up to 1300 °C in vacuum and 600 °C in air. The changes occurring on heat treatment in vacuum in these films around 600 °C have been correlated with the release of defects from the threefold network. Likewise, 950 °C temperature has been associated with the conversion of disordered tetrahedral bonding to a distorted trigonal one. The heat treatment in air shows that the microstructure induced due to lower ST is thermally more stable. ©1996 American Institute of Physics.
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