Sulfur Containing Reagent for Ion Flotation and Spectrophotometric Determination of Palladium(II)
作者:
S.E. Ghazy,
M.A. Kabil,
A.A. El-Asmy,
Y.A. Sherief,
期刊:
Analytical Letters
(Taylor Available online 1996)
卷期:
Volume 29,
issue 7
页码: 1215-1229
ISSN:0003-2719
年代: 1996
DOI:10.1080/00032719608001470
出版商: Taylor & Francis Group
关键词: Palladium determination;4-phenylthiosemicarbazide;oleic acid;flotation;spectrophotometry;solid complex.
数据来源: Taylor
摘要:
The recovery of palladium(II) from acidic aqueous solutions and sea water using 4-phenylthiosemicarbazide (HPTS) and oleic acid surfactant (HOL) has been studied by ionic flotation. Hydrogen ion concentration, foreign ions, temperature and reagent concentrations have been investigated for attaining the maximum efficiency of palladium(II) flotation. HPTS is used to develop a rapid and sensitive method for the spectrophotometric microdetermination of Pd(II). Various analytical parameters have been evaluated. Beer's law is obeyed over 2.0–14.5 ppm concentration range. The molar absorptivity of the formed 1:1 species is 0.49 x 104L mol−1cm−1at 300 nm. The ligand protonation constant and the stability constants of its complexes with Pd(II) have been determined potentiometrically. The method is successfully applied to determine directly the added Pd(II) to sea water without flotation. Square-planar geometry was proposed for the isolated solid complex. Also, the flotation mechanism is suggested.
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