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The Mechanism of Division of Small Liquid Systems Which Are the Seats of Physico‐Chemical Reactions

 

作者: N. Rashevsky,  

 

期刊: Journal of Applied Physics  (AIP Available online 1934)
卷期: Volume 5, issue 12  

页码: 374-379

 

ISSN:0021-8979

 

年代: 1934

 

DOI:10.1063/1.1745223

 

出版商: AIP

 

数据来源: AIP

 

摘要:

In continuation of a previous investigation, the mechanism of division of small liquid droplets, which are the seats of physico‐chemical reactions, is being studied now not from thermodynamical, but from the kinetic point of view. Thermodynamical considerations give us conditions under which the whole drop is less stable, than its two halves. It does not say however anything about the degree of stability. The present investigation makes this next step, and shows under what conditions a drop becomes so unstable, that an infinitesimal deformation will lead to a division. The critical sizes calculated here are close to those calculated by thermodynamical method. The importance of ``release phenomena'' and ``valve action'' in the cases considered is pointed out.

 

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