The glassy state in polymers
作者:
Geoffrey Gee,
期刊:
Contemporary Physics
(Taylor Available online 1970)
卷期:
Volume 11,
issue 4
页码: 313-334
ISSN:0010-7514
年代: 1970
DOI:10.1080/00107517008204410
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The transition between the liquid or rubbery state and the glassy state is not sharp, but a glass temperature can be defined in terms of measurements of volume or heat capacity. This temperature can be related to the relaxation regions in visco-elastic or dielectric behaviour. Theories of the glass transition relate this variously to molecular relaxations, to free volume and to excess enthalpy or entropy; these are not altogether mutually exclusive. Observed transition temperatures can be related qualitatively with molecular structure, but a quantitative treatment faces formidable difficulties. Properties of glassy polymers reflect the generally low cohesion and the frozen-in disorder and hole structure. Relaxation behaviour is observed in the vicinity of the glass temperature.
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