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Modeling Dynamic Phase Transitions in Ti and Zr

 

作者: C. W. Greeff,   P. A. Rigg,   M. D. Knudson,   R. S. Hixson,   G. T. Gray,  

 

期刊: AIP Conference Proceedings  (AIP Available online 1904)
卷期: Volume 706, issue 1  

页码: 209-212

 

ISSN:0094-243X

 

年代: 1904

 

DOI:10.1063/1.1780218

 

出版商: AIP

 

数据来源: AIP

 

摘要:

Both Ti and Zr exhibit phase transitions from the &agr; (hcp) to the &ohgr; phase at pressures of a few GPa. In addition, the Hugoniot of Zr shows a second phase transition at 23 GPa. We have developed multi‐phase equations of state for these metals based on ultrasonic, static compression, and shock data. The second transition in Zr is consistent with a phase diagram in which the high‐temperature and high‐pressure bcc phases are a single continuous phase. Time‐resolved experiments using plate impact and continuous magnetic loading are compared to simulations to investigate the kinetics of these phase transitions. Strong kinetic effects are observed in the &agr; ‐ &ohgr; transition in both metals, with the dynamic phase transition observed at pressures well above the equilibrium phase boundary. Data on Zr samples of varied purity are consistent with a strong reduction of the transformation rate by impurities. © 2004 American Institute of Physics

 

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