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Synthetic Studies Directed toward the Pseurotins. Part I. Synthesis of Related Furan‐3(2H)‐ones

 

作者: Matthys Dolder,   Xie Shao,   Christoph Tamm,  

 

期刊: Helvetica Chimica Acta  （WILEY Available online 1990）
卷期: Volume 73, issue 1  

页码: 63-68

 

ISSN:0018-019X

 

年代: 1990

 

DOI:10.1002/hlca.19900730106

 

出版商: WILEY‐VCH Verlag GmbH

 

数据来源: WILEY

 

摘要:

AbstractAccording to a general concept for the total synthesis of pseurotin A (1), a secondary metabolite ofPseudeurotium ovalisSTOLK, 5‐[(1S,2S,Z)‐1,2‐dihydroxyhex‐3‐enyl]‐2,2,4‐trimethylfuran‐3(2H)‐one (17) was prepared. It is a model substance for the substituted furan‐3(2H)‐one moiety of1. The aldol condensation of the aldehyde26, derived from D‐glucose, and the enolate of ketone2

 

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