The Influence of Surface Chemistry on the Development of Minor Species Profiles in the Premixed Boundary Layer Combustion of an H2/Air Mixture
作者:
PENELOPE MARKATOU,
LISAD. PFEFFERLE,
MITCHELLD. SMOOKE,
期刊:
Combustion Science and Technology
(Taylor Available online 1991)
卷期:
Volume 79,
issue 4-6
页码: 247-268
ISSN:0010-2202
年代: 1991
DOI:10.1080/00102209108951769
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The combustion of premixed hydrogen/air mixtures flowing over a hot catalytic and non-catalytic surface has been modelled using a modified Newton's method and an adaptive gridding algorithm for the solution of the governing boundary layer equations. Detailed transport, including thermophoretic effects, and gas phase chemical kinetics were included in the model. The surface boundary conditions in the catalytic case include a mass transport limited surface reaction of H2and O2to form H2Oand OH. The relative amounts of H,0 and OH were taken from available experimental data and were varied to test the effect of the amount of desorbed OH on radical profile shapes. Heat release and O-atom profiles exhibit a double peak as a result of OH desorption. The heat release in the catalytic case is significantly lower near the leading edge of the plate resulting in slower flame propagation into the boundary layer. Recombination reactions of the unstable species (O, OH, H, HO2, H2O2) on the wall were included in the non-catalytic case. The sticking coefficients of the recombination reactions were varied to test the effect of the recombination rate on radical profile shapes.
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