Synthesis and Reactions of Carbohydrate Trifluoro-Methanesulfonates (Carbohydrate Triplates)
作者:
RogerW. Binkley,
MichaelG. Ambrose,
期刊:
Journal of Carbohydrate Chemistry
(Taylor Available online 1984)
卷期:
Volume 3,
issue 1
页码: 1-49
ISSN:0732-8303
年代: 1984
DOI:10.1080/07328308408057896
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
During the past decade a new leaving group, the trifluoromethanesufonate (triflate), has been used increasingly in displacement reactions in carbohydrate chemistry*. The importance of this group has become progressively more apparent to the synthetic carbohydrate chemist as the examples of triflate displacement have increased. The number of applications of this reaction now has reached a sufficient magnitude that it seems appropriate to review what has been accomplished.
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