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Synthesis and Characterization of Poly-[2-methoxy-4,6-di(2,7-Naphthyloxy)-s-triazine]

 

作者: P.P. Shah,  

 

期刊: Journal of Macromolecular Science: Part A - Chemistry  (Taylor Available online 1984)
卷期: Volume 21, issue 6-7  

页码: 715-724

 

ISSN:0022-233X

 

年代: 1984

 

DOI:10.1080/00222338408077235

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

Poly[2-methoxy-4,6-di (2,7-naphthyloxy)-s-triazine] was synthesized by interfacial polycondensation of 2-methoxy-4,6-dichloro-s-triazine with 2,7-dihydroxy-naphthalene. The polymer was characterized by IR and UV spectra, dynamic mechanical analysis, differential scanning calorimetry, and thermogravimetric analysis. The polymer was fractionated by the fractional precipitation method and the fractions were characterized by viscometry and membrane osmometry. The polymer has a Tgof 175°C and is found to be stable up to 300°C in air. The polymer sample is found to degrade in air in two steps, and the energy of activation for the first step is around 25 kcal/mol.

 

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