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Kerr response of nematic liquids

 

作者: Alan R. Johnston,  

 

期刊: Journal of Applied Physics  (AIP Available online 1973)
卷期: Volume 44, issue 7  

页码: 2971-2974

 

ISSN:0021-8979

 

年代: 1973

 

DOI:10.1063/1.1662691

 

出版商: AIP

 

数据来源: AIP

 

摘要:

The Kerr response of seven nematic substances has been measured just above their nematic‐isotropic transition temperature, in their isotropic state. If the reciprocal of the Kerr constantBis plotted against temperature, a linear relationship analogous to the Curie‐Weiss dielectric relationship in ferroelectrics is found in all cases. The transient Kerr response—that is, the variation of induced birefringence with time in response to a field step—was also measured in three of the compounds. Inp‐(p‐ethoxybenzylidene) amino benzonitrile (EBAB), a maximum Kerr constant of 175×10−10cm2V−1was observed, together with a response time of 13 nsec. The extremely short response time indicates that molecular association does not take place. On the other hand,n‐(p‐methoxybenzylidene)‐p‐butylaniline (MBBA) under similar conditions showed a response time of 3 &mgr;sec, indicating that a high degree of association does take place in the isotropic phase.

 

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