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Manifestation of biquadratic coupling in the smectic C* phase soft mode dielectric response

 

作者: F. Gouda,   T. Carlsson,   G. Andersson,   S.T. Lagerwall,   B. Stebler,  

 

期刊: Liquid Crystals  (Taylor Available online 1994)
卷期: Volume 16, issue 2  

页码: 315-322

 

ISSN:0267-8292

 

年代: 1994

 

DOI:10.1080/02678299408029155

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

The soft mode dielectric response of three ferroelectric chiral smectic C* substances is studied in the vicinity of the smectic C*-smectic A* phase transition. For some substances the soft mode dielectric strength exhibits a pronounced anomaly in the C* phase just below the phase transition. We show how this anomaly can be systematically correlated with a corresponding anomaly in the experimentally determined ratio of spontaneous polarization over tilt. By comparing the experimental results with the theoretical predictions of an extended Landau model, we demonstrate how the crossover behaviour of the system can be interpreted as being the consequence of the presence of a biquadratic coupling between tilt and polarization in the Landau free-energy of the system.

 

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