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Palladium‐catalyzed hydrosilylation of silyl‐substituted butadienes

 

作者: Wu‐Wang Weng,   Ruey‐Min Chen,   Tien‐Yau Luh,  

 

期刊: Heteroatom Chemistry  (WILEY Available online 1995)
卷期: Volume 6, issue 1  

页码: 15-18

 

ISSN:1042-7163

 

年代: 1995

 

DOI:10.1002/hc.520060106

 

出版商: VCH Publishers, Inc.

 

数据来源: WILEY

 

摘要:

AbstractPalladium‐catalyzed hydrosilylation of silyl‐substituted butadienes1and2with MeSiCl2H has been investigated. Both steric effects and the presence of an aryl substituent affect the regiochemistry of the hydrosilylation reaction. Hydrosilylation of siloxanetethered bis‐dienes9exhibits high regio‐ and diastereosele

 

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