ISSN 0300-9238 JCFTAR 84(4) 885-1 285 (1 988) 885 899 91 7 923 93 1 94 1 95 1 959 969 979 993 1013 1025 033 047 057 065 1075 1083 30 JOURNAL OF THE CHEMICAL SOCIETY Faraday Transactions I Physical Chemistry in Condensed Phases CONTENTS Glutamic Acid-Hydrogen Phosphate Hydrogen Bonds. Proton Polarizability and Proton Transfer as a Function of the Cations Present and of the Degree of Hydration : Infrared Investigations The Interaction between Ions and the Activation Barrier of Elementary Events of Crystal Growth and Evaporation V. K. W. Cheng, B. A. W. Coller and E. R. Smith Hydrogenolysis of Ethane. Part 2.-Initial Rate Measurements over Ni and Pd Catalysts Mechanistic Aspects of Oxidative Coupling of Methane over LaAlO, T. Tagawa and H. Imai Measurements of the Electrolyte Conductivity of Alkali-metal Perchlorates and LiNO, in Acetone at 25 "C N. Schmelzer, J.Einfeldt and M. Grigo Electrochemical Regeneration of NAD+. A New Evaluation of its Actual Yield J. Bonnefoy, J. Moiroux, J-M. Lava1 and C. Bourdillon Interactions between Metal Cations and the Ionophore Lasalocid. Part 1 .--Complexation of Alkaline-earth-metal Cations by Lasalocid, Bromo- lasalocid and Salicylic Acid in Methanol J. Juillard , C. Tissier and G. Jeminet Interactions between Metal Cations and the Ionophore Lasalocid. Part 2.-Gibbs Functions, Enthalpies and Entropies for Complexation of Alkali- metal Cations by Lasalocid and Bromolasalocid Interactions betwen Metal Cations and the Ionophore Lasalocid. Part 3.-Interactions of Lasalocid with Mn2+, Fe2+, Co2+, Ni2+ and Zn2+ in Methanol P.Laubry, C. Tissier, G. Mousset and J. Juillard Solvation Thermodynamics of Ethidium Bromide in Mixed Solvents G. Varani, G. Chirico and G. Baldini The Brusselator Model of Oscillatory Reactions. Relationships between Two- variable and Four-variable Models with Rigorous Application of Mass Conservation and Detailed Balance The Brusselator: It does Oscillate all the same R. Lefever, G. Nicolis and P. Borckmans Effect of the Polymer Backbone on the Ligand Substitution Reaction of a Macromolecule-Metal Complex. Acid and Base Hydrolyses of the Polymer- bound Cobalt(rr1) Complexes Water Dynamics and Aggregate Structure in Reversed Micelles at Sub-zero Temperatures. A Deuteron Spin Relaxation Study P-0. Quist and B. Halle Molar Gibbs Energies of Transfer for Cu2+, Zn2+, Cd2+ and Pb2+ G.Gritzner Conductance Studies of Tetra-alkylammonium Bromides in 2-Methoxyethanol at 25 "C D. Das Gupta, S. Das and D. K. Hazra Ion-exchange Equilibria between Solid Aluminium Pectinates and Ca, Mn", Cu" and Fe*** Ions in Aqueous Solution R. A. Jorge and A. P. Chagas Studies on the Reactivity of 'OH Radicals in Non-aqueous Solvents using Laser Flash Photolysis T. Vidoczy, N. N. Blinov, G. Irinyi and D. Gal Preferential Solvation of the Europium(rrr) Ion in Water-Non-aqueous Solvent Mixtures. A Luminescence Lifetime Study F. Tanaka, Y. Kawasaki and S. Y amashita U. Burget and G. Zundel S. Kristyan and J. Szamosi Y. Pointud and J. Juillard P. Gray, S. K. Scott and J. H. Merkin Y. Kurimura, Y. Takagi and M. Saito FAR 1Con tents Selective Conversion of Methanol into Aromatic Hydrocarbons over Zinc- exchanged ZSM-5 Zeolites Y.Ono, H. Adachi and Y. Senoda Oxidation of Thiocyanate and Iodide Ions by Hydrogen Atoms in Acid Solutions. A Pulse Radiolysis Study A. J. Elliot, S. Geertsen and G. V. Buxton Ionisation Constants of 'OH and HO; in Aqueous Solution up to 200 "C. A Pulse Radiolysis Study Practical Limitations of Polyacetylene used as a High-power-density Cathode J. B. Schlenoff and J. C. W. Chien The Partitioning of Proteins between Water-in-oil Microemulsions and Conjugate Aqueous Phases Association Constants for the Electron-donor-Acceptor Complexes of Indole and 1 -Methylindole with 1 -(2,4,6-Trinitrophenyl)propan-2-one from Nuclear Magnetic Resonance Shift Measurements.An Anomalous Scatchard Plot J. A. Chudek, R. Foster, R. L. Mackay, F. M. Page and D. R. Twiselton Ionic Solvation in Water-Cosolvent Mixtures. Part 15.-Free Energies of Transfer of Single Ions from Water into Water-Dimethylformamide Mixtures I. M. Sidahmed and C. F. Wells Time-resolved Analysis of a ' Crystal-like ' Structure-forming Process of a Monodisperse Polystyrene Sphere as studied by Rapid-scanning Spectro- photometry T. Okubo Deformation of ' Crystal-like ' Structure of a Monodisperse Polystyrene Sphere under Shear Rate as studied by the Transmitted-light Spectrum Method T. Okubo Electron Spin Resonance Studies of the CS;- Radical Anion, and its Conjugate Acid The Formation of P-Muonium-substituted Cyclopentyl and Cycloheptyl Radicals, and the Significance of the A I / A , Isotope Ratio in Relation to the Conformations of Muonium-substituted Alkyl Radicals C. J.Rhodes and M. C. R. Symons Enhanced Dissolution of PuO, in Nitric Acid using Uranium(1v) Differences in Thermal and Mechanochemical Polymorphism. Effects of Impurity on the System Aragonite-Calcite Light-scattering Studies of Aggregation in Aqueous Solutions of Poly(viny1 alcohol co-vinyl acetate) Copolymer N. J. Crowther and D. Eagland Combined Study of Coagulation Kinetics and Close-range Aggregate Structure A. Lips and R. M. Duckworth Solubilities of Salts and Kinetics of Reactions involving Inorganic Complex Ions in Aqueous Acetone Mixtures. Derivation of Transfer Chemical Potentials for Ions in these Aqueous Mixtures at Ambient Pressure and 298.2 K M. J. Blandamer, B. Briggs, J. Burgess, P. Guardado, S. Radulovic and C. D. Hubbard Kinetics of the Dissociation Reaction of Ferricenium Tri-iodide in Benzene Solution S. R. Logan and M. R. Welsh Study of the Conformational Equilibria between Rotational Isomers using Ultrasonic Relaxation and Raman Spectroscopy. Part 2.-Di- and Tri- halogenoalkanes H. Nomura, S. Koda and K. Hamada Volumetric and Infrared Studies of the Adsorption of Gaseous Benzene, Toluene and Chlorobenzene by Zinc Oxide M. Nagao and K. Matsuoka G. V. Buxton, N. D. Wood and (in part) S. Dyster P. D. I. Fletcher and D. Parrott J. S. Lea and M. C. R. Symons A. Inoue T. Isobe and M. Senna 1091 1101 1113 1123 1131 1145 1153 1163 1171 1181 1187 1195 1199 121 1 1223 1243 1259 1267 1277