首页   按字顺浏览 期刊浏览 卷期浏览 Selective nucleophilic displacement of a methoxy group in 1,2,3‐trimethoxybenzenes
Selective nucleophilic displacement of a methoxy group in 1,2,3‐trimethoxybenzenes

 

作者: P. H. M. Budzelaar,   J. A. van Doorn,  

 

期刊: Recueil des Travaux Chimiques des Pays‐Bas  （WILEY Available online 1990）
卷期: Volume 109, issue 7‐8  

页码: 443-445

 

ISSN:0165-0513

 

年代: 1990

 

DOI:10.1002/recl.19901090710

 

出版商: WILEY‐VCH Verlag

 

数据来源: WILEY

 

摘要:

AbstractA methoxy group in 1,2, 3‐trimethoxybenzenes can be readily displaced by a butyl group via reaction with butyllithium in hexane. The reaction probably proceeds via an addition‐elimination mechanism. There appears to be a qualitative relation between the coefficient of the LUMO at the central C‐O carbon atom and the rate of the rea

 

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