REMARKS ON THE CLASSICAL THEORY OF CAPILLARIT
作者:
B.V. Toshev,
期刊:
Journal of Dispersion Science and Technology
(Taylor Available online 1997)
卷期:
Volume 18,
issue 6-7
页码: 801-812
ISSN:0193-2691
年代: 1997
DOI:10.1080/01932699708943773
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The present paper describes a new way of presentation of the classical theory of capillarity. An approach based on the Ω-potential thermodynamic formalism is used. An explicit definition of the Gibbs excess quantities of the extensive thermodynamic functions is proposed. It is emphasized that the Ω-potential is the only extensive thermodynamic function which, when defined as an excess quantity, is not in fact such a quantity. It holds for the case of two-phase plane-interface equilibrium systems. The work of transformation of a homogeneous system into a heterogeneous one at given conditions, (ΔΩ)T,V,μ, is defined by means of Eq.(39). Different capillary systems and different thermodynamic models for their description can be unified on the basis of Eq.(39).
点击下载:
PDF (228KB)
返 回