Permeation of gases at high pressures
作者:
S.A. Stern,
S. M. Fang,
R.M. Jobbins,
期刊:
Journal of Macromolecular Science, Part B
(Taylor Available online 1971)
卷期:
Volume 5,
issue 1
页码: 41-69
ISSN:0022-2348
年代: 1971
DOI:10.1080/00222347108212520
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The permeation of He, N2, CH4, C2H6, C2H4, CO2, and N2O through polyethylene membranes has been studied at pressures up to 60 atm and at temperatures between −10° and 60° C. The experimental temperature range encompassed the critical temperature of the last four penetrants. The mean permeability coefficient,P, for C2H6, C2H4, CO2, and N2O exhibited an exponential dependence on pressure at reduced penetrant temperatures below and near unity. This dependence decreased with increasing reduced temperature. The values ofPfor CH4, which were obtained at reduced temperatures above unity, were essentially constant over the entire pressure range. Finally, theP's for N2and He, which were measured at the highest reduced temperatures, appeared to decrease slightly with increasing pressure. Possible causes for the observed behavior are discussed, and a new correlation for the pressure dependence of the permeability coefficients is presented.
点击下载:
PDF (946KB)
返 回