Pulse radiolysis study of the reaction of OH radicals with C2H4over the temperature range 343–1173 K
作者:
An‐Dong Liu,
William A. Mulac,
Charles D. Jonah,
期刊:
International Journal of Chemical Kinetics
(WILEY Available online 1987)
卷期:
Volume 19,
issue 1
页码: 25-34
ISSN:0538-8066
年代: 1987
DOI:10.1002/kin.550190104
出版商: John Wiley&Sons, Inc.
数据来源: WILEY
摘要:
AbstractThe reaction of OH and OD radicals with ethylene in the presence of 1 atm argon and 6 Torr water vapor was studied in the temperature range 343–1173 K. The results reveal three kinetically separate temperature regions: (1) 343–563 K, where the disappearance of OH radical is dominated by the addition of OH to the double bond of ethylene; (2) 563–748 K, where concurrent reactions of addition, the reverse reaction of addition and H‐atom abstraction is dominant; and (3) 748–1173 K, where H‐atom abstraction is likely the main reaction. The rate for hydrogen abstraction is 2.4 × 10−11exp[(−2104 ± 125)/T] cm3/molec‐s (for OD 2.1 × 10−11exp[(−2130 ± 172)/T] cm3/molec‐s). There was no obvious pyrolysis of ethylene below 1073 K. The study of OD radical with ethylene s
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