A High Pressure Temperature‐Jump Apparatus
作者:
Andrew D. Yu,
Mario D. Waissbluth,
Richard A. Grieger,
期刊:
Review of Scientific Instruments
(AIP Available online 1973)
卷期:
Volume 44,
issue 9
页码: 1390-1392
ISSN:0034-6748
年代: 1973
DOI:10.1063/1.1686392
出版商: AIP
数据来源: AIP
摘要:
A technique is described for carrying out temperature‐jump experiments at pressures up to 1000 atm, thus allowing the measurement of activation volumes for reactions in the &mgr;sec‐sec range. The main features of the new technique are an electrical lead which has been tested to 2000 atm and 10 000 V ungrounded electrodes, and a flexible cell to transmit pressure from the external fluid to the solution.
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