The Thermotropic Liquid-Crystalline Properties of Some Straight Chain Carbohydrate Amphiphiles
作者:
J.W. Goodby,
M.A. Marcus,
E. Chin,
P.L. Finn,
B. Pfannemuller,
期刊:
Liquid Crystals
(Taylor Available online 1988)
卷期:
Volume 3,
issue 11
页码: 1569-1581
ISSN:0267-8292
年代: 1988
DOI:10.1080/02678298808086696
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
A variety of homologous 1-deoxy-1-(N-methylalkamido)-D-glucitols were prepared and their liquid crystal phases characterized. In this study the thermotropic liquid-crystalline properties of these materials are investigated. The mesophases formed are shown to be of the smectic A class with an interdigitated bilayer ordering of the constituent molecules. This ordering is thought to be stabilized by hydrogen-bonding between neighbouring carbohydrate moieties. The properties of these materials are compared with those of other closely related acyclic carbohydrates.
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