X-Ray Spectra of Iron Phosphonates
作者:
JoelM. Klein,
JosephJ. Kokalas,
期刊:
Spectroscopy Letters
(Taylor Available online 1972)
卷期:
Volume 5,
issue 12
页码: 497-500
ISSN:0038-7010
年代: 1972
DOI:10.1080/00387017208065420
出版商: Taylor & Francis Group
关键词: Phosphonates;d-spacing;steric effect;x-ray spectra;iron
数据来源: Taylor
摘要:
The reaction of dialkyl alkylphosphonates with trivalent metal chlorides has recently been reported (1,2). The typical products of these reactions is a solid which is insoluble in most organic solvents and water. A monomeric structure was postulated for the iron phosphonates(1), while polynuclear structure was proposed for titanium, vanadium, and chromium phosphonates(2). Infrared(1) and Mossbauer-effect(3) studies were unable to differentiate between the monomeric or polynuclear structure for the iron phosphonates, In an attempt to further characterize the iron phosphonates, an x-ray diffration study was undertaken. The results of these studies are reported herein.
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