AbstractThe present article describes the discovery of a new procedure for aldol condensations for the preparation of α,β‐unsaturated carbonyl compoundsG. Wittig,H. Pommer, andW. Stilz, German Patent 1199252 (April 5, 1963), BASF; Chem. Abstr.63, P 1739c (1965).. The scope of this process is demonstrated by many examples, including some from the natural products sector; at the same time, however, these examples also mark its limitations. The metalated Schiff's bases may be classified as ambident anions; this also explains acylations on the nitrogen. A comparison of the new directed aldol condensation with the formation of unsaturated carbonyl compounds through olefination via phosphorylids shows that the latter method fails when a ketone is used as the substrate. This is where the described procedure using metalated Schiff's bases proves its va