首页   按字顺浏览 期刊浏览 卷期浏览 Kinetics of Spherulite Growth in High Polymers
Kinetics of Spherulite Growth in High Polymers

 

作者: Bruce B. Burnett,   W. F. McDevit,  

 

期刊: Journal of Applied Physics  (AIP Available online 1957)
卷期: Volume 28, issue 10  

页码: 1101-1105

 

ISSN:0021-8979

 

年代: 1957

 

DOI:10.1063/1.1722586

 

出版商: AIP

 

数据来源: AIP

 

摘要:

Spherulite growth rates have been measured in two polyamides, 66 and 6 nylon, at temperatures ranging from 38 to 141° below the melting points using a moving photomicrographic technique. At constant temperature, the spherulite radius increases at a constant rate. This isothermal growth rate constant is temperature dependent, having low values just below the melting point, passing through a maximum on further supercooling and decreasing to negligible values at room temperature. These facts indicate that spherulite growth is not a diffusion controlled process. A reasonable interpretation of the data has been obtained using the concept of growth by two‐dimensional surface nucleation. A theoretical expression for the temperature dependence of the growth rate based on this concept has given good agreement with the experimentally determined values.

 

点击下载:  PDF (390KB)



返 回