摘要:
AbstractThe reactions of acetonitrile (II) with the anions of the two isoelectronic arachno clusters (I) and (IV) are explored and found to result in reduction of the nitrile and either the incorporation of a CN unit into the cage framework giving the air‐stable cluster (III) or a one‐carbon insertion accompanied by deamination yielding the new three‐carbon nido‐carborane (V) as the sole product.
ISSN:0931-7597
DOI:10.1002/chin.198939213
出版商:WILEY‐VCH Verlag GmbH
年代:2016
数据来源: WILEY