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A convenient synthesis ofL‐1‐methylhistidine andL‐1‐ethylhistidine |
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Recueil des Travaux Chimiques des Pays‐Bas,
Volume 91,
Issue 3,
1972,
Page 246-250
H. C. Beyerman,
L. Maat,
A. van Zon,
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摘要:
AbstractAlkylation of the easily accessible methyl ester ofL‐Na,3‐dibenzoylhistidine with the aid of trimethyl‐ and triethyloxonium fluoroborate followed by decomposition with water and acid hydrolysis yieldedL‐1 ‐methyl‐ andL‐1‐ethylhistidine respectively. Comparison with naturalL‐1‐methylhistidine confirmed the structure
ISSN:0165-0513
DOI:10.1002/recl.19720910302
出版商:WILEY‐VCH Verlag
年代:1972
数据来源: WILEY
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2. |
Some remarks concerning the interpretation of shifts in carbon(1s) electron binding energies |
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Recueil des Travaux Chimiques des Pays‐Bas,
Volume 91,
Issue 3,
1972,
Page 251-260
J. Bus,
S. de Jong,
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摘要:
AbstractThe carbon (1s) electron binding energies (Eb) of methyl acetate (CH3:285.6, CO: 289.5 and OCH3: 286.5 eV) correlate well with CNDO/2‐charges (slope 5.6 eV/unit charge), with Pauling charges (slope 5.1) and with Extended Hückel charges (slope 2.4).If the Eb‐values are corrected for molecular potentials (V), again good correlations are found (slope 22.0, 20.9 and 18.6 resp.). Because it did not make much difference which method was used for calculating charges (q), tests have been made to establish whether charge calculations based on electronegativities could be used for a large series of C(1s) binding energies. For adjacent charges of equal signs, a correction was introduced and it was also found that Jolly's (or Johnson's) electronegativity values gave better results than the Pauling values.Resonably good correlations were obtained for the function Eb= α + βq + κV with κ = 0, κ = 1 and κ ≠ 0. Introduction of a γq2term did not improve the correlation. The best fit was obtained with Eb= 285.3 + 11.75 q + 0.48 V ±
ISSN:0165-0513
DOI:10.1002/recl.19720910303
出版商:WILEY‐VCH Verlag
年代:1972
数据来源: WILEY
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3. |
Masthead |
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Recueil des Travaux Chimiques des Pays‐Bas,
Volume 91,
Issue 3,
1972,
Page -
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PDF (25KB)
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ISSN:0165-0513
DOI:10.1002/recl.19720910301
出版商:WILEY‐VCH Verlag
年代:1972
数据来源: WILEY
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