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1. |
Graphical Abstract (Angew. Chem. Int. Ed. Engl. 22/1995) |
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Angewandte Chemie International Edition in English,
Volume 34,
Issue 22,
1995,
Page 2429-2435
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ISSN:0570-0833
DOI:10.1002/anie.199524291
出版商:Hüthig&Wepf Verlag
年代:1995
数据来源: WILEY
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2. |
Synthetic Aspects of Metal‐Catalyzed Oxidations of Amines and Related Reactions |
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Angewandte Chemie International Edition in English,
Volume 34,
Issue 22,
1995,
Page 2443-2465
Shun‐Ichi Murahashi,
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摘要:
AbstractThe metabolism of amines is governed by a variety of enzymes such as amine oxidase, flavoenzyme, and cytochrome P‐450. A wide variety of compounds are produced such as ammonia and alkaloids in selective and clean oxidation reactions that proceed under mild reaction conditions. Simulation of the functions of these enzymes with simple transition metal complex catalysts may lead to the discovery of biomimetic, catalytic oxidations of amines and related compounds. Indeed, metal complex catalyzed oxidations have been found to proceed with high efficiency. The first section of this review discusses the dehydrogenative oxidations of amines with transition metal catalysts by transition metal catalysts that simulate amine oxidase. The second section highlights the catalytic oxidation of secondary amines to nitrones by simulation of flavoenzymes. The third section describes the simulation of the function of cytochrome P‐450 with lowvalent ruthenium complexes and peroxides. Biomimetic ruthenium‐catalyzed oxidations of tertiary amines, secondary amines, and other substrates such as amides, β‐lactams, nitriles, alcohols, alkenes, ketones, and even nonactivated hydrocarbons can be performed selectively under mild conditions. These three general approaches provide highly useful strategies for synthesis of fine chemicals and biologically active compounds such as alkaloids, amino acids, and
ISSN:0570-0833
DOI:10.1002/anie.199524431
出版商:Hüthig&Wepf Verlag
年代:1995
数据来源: WILEY
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3. |
Cyclopentadienyl‐Free Organolanthanide Chemistry |
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Angewandte Chemie International Edition in English,
Volume 34,
Issue 22,
1995,
Page 2466-2488
Frank T. Edelmann,
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摘要:
AbstractDuring the past ten years the organometallic chemistry of the lanthanides has witnessed enormous growth. One of the main reasons for this development was the finding that lanthanide metallocenes can exhibit an unusually high catalytic activity. Considerable advances have also been achieved in the chemistry of organolanthanide complexes that are not stabilized by cyclopentadienyl ligands. For example, the successful synthesis of the first unsolvated homoleptic trialkyllanthanides, [Ln{CH(SiMe3)2}3], has recently been reported. Anionic allyl complexes of the lanthanides show promising catalytic properties and cyclooctatetraene complexes of these elements are also under active investigation. This review is intended to provide an overview of this rapidly developing area of research.
ISSN:0570-0833
DOI:10.1002/anie.199524661
出版商:Hüthig&Wepf Verlag
年代:1995
数据来源: WILEY
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4. |
New Surprises in Metal Carbonyl Chemistry |
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Angewandte Chemie International Edition in English,
Volume 34,
Issue 22,
1995,
Page 2489-2491
John E. Ellis,
Wolfgang Beck,
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ISSN:0570-0833
DOI:10.1002/anie.199524891
出版商:Hüthig&Wepf Verlag
年代:1995
数据来源: WILEY
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5. |
Sunlight‐Damaged DNA Repaired with Sunlight |
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Angewandte Chemie International Edition in English,
Volume 34,
Issue 22,
1995,
Page 2491-2494
Thomas Carell,
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ISSN:0570-0833
DOI:10.1002/anie.199524911
出版商:Hüthig&Wepf Verlag
年代:1995
数据来源: WILEY
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6. |
Reactions of Neopentyl 2,2,2,‐Trifluoroethanesulfonate (Tresylate) with Nucleophiles: A Model Study for the Coupling of Nucleophiles with Tresyl Agarose |
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Angewandte Chemie International Edition in English,
Volume 34,
Issue 22,
1995,
Page 2495-2495
James F. King,
Manjinder Singh Gill,
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ISSN:0570-0833
DOI:10.1002/anie.199524952
出版商:Hüthig&Wepf Verlag
年代:1995
数据来源: WILEY
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7. |
A Novel Method for the Synthesis of Isocyanates Under Mild Conditions |
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Angewandte Chemie International Edition in English,
Volume 34,
Issue 22,
1995,
Page 2497-2500
Hans‐Joachim Knölker,
Tobias Braxmeier,
Georg Schlechtingen,
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ISSN:0570-0833
DOI:10.1002/anie.199524971
出版商:Hüthig&Wepf Verlag
年代:1995
数据来源: WILEY
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8. |
PH‐Functionalized Phosphenium Complexes [C5R5(OC)2WP(H)R′] (R′ =tBu, sMes): Synthesis, Isomerization, and Transformation into Hydrido Complexes Containing atBuP(H)OH Ligand |
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Angewandte Chemie International Edition in English,
Volume 34,
Issue 22,
1995,
Page 2500-2502
Wolfgang Malisch,
Ulrich‐Andreas Hirth,
Klaus Grün,
Martin Schmeusser,
Oliver Fey,
Udo Weis,
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ISSN:0570-0833
DOI:10.1002/anie.199525001
出版商:Hüthig&Wepf Verlag
年代:1995
数据来源: WILEY
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9. |
Oxidative Transformations of a Pyrimidalized 1,5‐Diene |
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Angewandte Chemie International Edition in English,
Volume 34,
Issue 22,
1995,
Page 2502-2504
Gerald Dyker,
Jutta Körning,
Peter G. Jones,
Peter Bubenitschek,
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ISSN:0570-0833
DOI:10.1002/anie.199525021
出版商:Hüthig&Wepf Verlag
年代:1995
数据来源: WILEY
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10. |
Soluble Aluminosilicates with Frameworks of Minerals |
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Angewandte Chemie International Edition in English,
Volume 34,
Issue 22,
1995,
Page 2504-2506
Mavis L. Montero,
Andreas Voigt,
Markus Teichert,
Isabel Usón,
Herbert W. Roesky,
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ISSN:0570-0833
DOI:10.1002/anie.199525041
出版商:Hüthig&Wepf Verlag
年代:1995
数据来源: WILEY
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