1. |
Olefin Alkylation in Biosynthesis |
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Angewandte Chemie International Edition in English,
Volume 7,
Issue 12,
1968,
Page 903-911
J. W. Cornforth,
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摘要:
AbstractStereochemical studies, made possible by asymmetric labeling with hydrogen isotopes, have led to the hypothesis that enzymic association of C5units in polysoprenoid synthesis is not a concerted process but proceeds in two steps: a trans 1,2‐addition to an olefin followed by a trans 1,2‐elimination. It is shown that similar mechanisms can also explain the cyclization of squalene epoxide to tetracyclic and pentacyclic triterpeno
ISSN:0570-0833
DOI:10.1002/anie.196809031
出版商:Hüthig&Wepf Verlag
年代:1968
数据来源: WILEY
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2. |
Crystallization during Polymerization |
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Angewandte Chemie International Edition in English,
Volume 7,
Issue 12,
1968,
Page 912-919
B. Wunderlich,
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摘要:
AbstractSimultaneous as well as successive polymerization and crystallization is possible. While crystallization after polymerization usually produces folded chain lamellar crystals, crystallzation during polymerization frequently produces fibrillar extended chain crystals.
ISSN:0570-0833
DOI:10.1002/anie.196809121
出版商:Hüthig&Wepf Verlag
年代:1968
数据来源: WILEY
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3. |
The Gabriel Synthesis of Primary Amines |
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Angewandte Chemie International Edition in English,
Volume 7,
Issue 12,
1968,
Page 919-930
M. S. Gibson,
R. W. Bradshaw,
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摘要:
AbstractReaction of potassium phthalimide with halogenoalkanes and with a variety of other alkylating agents leads to the N‐alkylphthalimide. N‐Substituted phthalimides may be converted into the corresponding primary amine by hydrolysis or hydrazinolysis. The scope and limitations of these reactions, which together constitute the Gabriel Synthesis of primary amines, are revie
ISSN:0570-0833
DOI:10.1002/anie.196809191
出版商:Hüthig&Wepf Verlag
年代:1968
数据来源: WILEY
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4. |
Kinetic Studies on Substitution Reactions of Carbonylmetal Complexes |
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Angewandte Chemie International Edition in English,
Volume 7,
Issue 12,
1968,
Page 930-941
H. Werner,
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摘要:
AbstractKinetic studies of substitution reactions of carbonylmetals and of carbonylmetal derivatives in which other ligands (n or π donors) besides CO are bound to the metal atom have recently attracted great interest, and the results of these investigations throw a new light on theoretical and preparative problems. The substitution mechanism is determined mainly by steric and electronic factors
ISSN:0570-0833
DOI:10.1002/anie.196809301
出版商:Hüthig&Wepf Verlag
年代:1968
数据来源: WILEY
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5. |
A New Synthesis of Isocyanates and Isothiocyanates |
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Angewandte Chemie International Edition in English,
Volume 7,
Issue 12,
1968,
Page 941-941
G. Greber,
H. R. Kricheldorf,
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ISSN:0570-0833
DOI:10.1002/anie.196809411
出版商:Hüthig&Wepf Verlag
年代:1968
数据来源: WILEY
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6. |
Asymmetric Catalytic Hydrogenation with an Optically Active Phosphinerhodium Complex in Homogeneous Solution |
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Angewandte Chemie International Edition in English,
Volume 7,
Issue 12,
1968,
Page 942-942
L. Horner,
H. Siegel,
H. Büthe,
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ISSN:0570-0833
DOI:10.1002/anie.196809422
出版商:Hüthig&Wepf Verlag
年代:1968
数据来源: WILEY
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7. |
Unusual Formation of the Unusual 1,2,8,9‐Tetraaza‐1,8‐cyclotetradecadiene‐3,10‐diol System and its 5,12‐Dioxa Analog |
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Angewandte Chemie International Edition in English,
Volume 7,
Issue 12,
1968,
Page 943-944
S. Hünig,
J. Cramer,
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ISSN:0570-0833
DOI:10.1002/anie.196809432
出版商:Hüthig&Wepf Verlag
年代:1968
数据来源: WILEY
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8. |
Crystal Structure of 1,2,8,9‐Tetraaza‐1,8‐cyclotetradecadien‐3,10‐ylene Diacetate |
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Angewandte Chemie International Edition in English,
Volume 7,
Issue 12,
1968,
Page 944-945
R. Allmann,
I. Kawada,
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ISSN:0570-0833
DOI:10.1002/anie.196809441
出版商:Hüthig&Wepf Verlag
年代:1968
数据来源: WILEY
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9. |
New Hydrazyls of Low Molecular Weight and Polymeric Hydrazyls |
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Angewandte Chemie International Edition in English,
Volume 7,
Issue 12,
1968,
Page 945-946
D. Braun,
G. Peschk,
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ISSN:0570-0833
DOI:10.1002/anie.196809451
出版商:Hüthig&Wepf Verlag
年代:1968
数据来源: WILEY
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10. |
Pb(H2PO4)4·(C6H5)3PO, Lead(IV) Tetrakis(dihydrogen phosphate) Stablized by Triphenylphosphine Oxide |
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Angewandte Chemie International Edition in English,
Volume 7,
Issue 12,
1968,
Page 946-947
F. Huber,
M. S. A. El‐Meligy,
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ISSN:0570-0833
DOI:10.1002/anie.196809462
出版商:Hüthig&Wepf Verlag
年代:1968
数据来源: WILEY
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