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1. |
Introduction |
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Polymer Engineering&Science,
Volume 29,
Issue 5,
1989,
Page 277-277
Sue Ann Bidstrup,
R. Bruce Prime,
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PDF (86KB)
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ISSN:0032-3888
DOI:10.1002/pen.760290502
出版商:Society of Plastics Engineers
年代:1989
数据来源: WILEY
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2. |
Simultaneous dielectric and dynamic mechanical analysis of thermosetting polymers |
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Polymer Engineering&Science,
Volume 29,
Issue 5,
1989,
Page 278-284
Jeffrey Gotro,
Michael Yandrasits,
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PDF (687KB)
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摘要:
AbstractThis work presents a new method to measure simultaneously the dielectric loss factor and viscosity of thermosetting polymers during various cure cycles. A microdielectric sensor was mounted in the bottom plate of a parallel plate rheometer. Three types of high performance laminating resins were investigated. During non‐isothermal curing, dipole peaks were found to correspond to softening/devitrification, the maximum in the loss factor followed the same heating rate dependence as the minimum in the viscosity, and dipole peaks were observed to correlate with vitrification when the cure temperature was below the ultimate glass transition temperature of the resi
ISSN:0032-3888
DOI:10.1002/pen.760290503
出版商:Society of Plastics Engineers
年代:1989
数据来源: WILEY
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3. |
Use of the frequency dependence of the impedance to monitor viscosity during cure |
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Polymer Engineering&Science,
Volume 29,
Issue 5,
1989,
Page 285-289
D. Kranbuehl,
S. Delos,
M. Hoff,
P. Haverty,
W. Freeman,
R. Hoffman,
J. Godfrey,
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PDF (487KB)
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摘要:
AbstractThe ability to conveniently and continuously measure the processing properties of polymer resins is important both to the resin supplier and to the fabricator. Frequency dependent electromagnetic sensors (FDEMS) provide anin‐situtechnique for continuous measurement of the resin's rheological changes both in a laboratory press and in manufacturing tools in an autoclave. In this paper the frequency dependence of ϵ*(w) is used to quantitatively monitor the viscosity for a tetraglycidyl 4,4′‐diaminodiphenyl methane (TGDDM) amine epoxy, to quantitatively monitor the viscosity during processing In a styrene‐polyester resin, and to monitor the cure process in an autoclave during cure of a high temperature polyimide‐graphite prepreg. In addition, the technique is used to measure the viscosity at various ply positions in a thick TGDDM graphite epoxy laminate during processing in an
ISSN:0032-3888
DOI:10.1002/pen.760290504
出版商:Society of Plastics Engineers
年代:1989
数据来源: WILEY
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4. |
Monitoring the cure of a composite matrix resin with microdielectrometry |
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Polymer Engineering&Science,
Volume 29,
Issue 5,
1989,
Page 290-294
Wayne W. Bidstrup,
Stephen D. Senturia,
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PDF (404KB)
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摘要:
AbstractThis paper presents a study of the cure of glass and graphite fiber epoxy composites using dielectric monitoring techniques. Initial results reported here deal with the neat resin and the relationship between its conductivity and corresponding changes in glass transition temperature during cure.
ISSN:0032-3888
DOI:10.1002/pen.760290505
出版商:Society of Plastics Engineers
年代:1989
数据来源: WILEY
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5. |
Isothermal and temperature programmed kinetic studies of thermosets |
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Polymer Engineering&Science,
Volume 29,
Issue 5,
1989,
Page 295-301
V. M. González‐Romero,
N. Casillas,
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PDF (530KB)
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摘要:
AbstractDifferential Scanning Calorimetry (DSC) is a popular method for the characterization of the cure kinetics of thermosetting materials. The experiments may be carried out under isothermal or temperature program modes. Several authors have pointed out the fact that the kinetic rate expressions for non‐isothermal experiments must be different from the isothermal ones; however, this fact has been neglected in practice. In this work, we present a kinetic characterization of a thermosetting system using a phenomenological model for the reaction rate expression and DSC data from isothermal and non‐isothermal experiments. In general, thermosetting materials exhibit the vitrification phenomenon which stops the reaction before complete conversion is achieved. Vitrification is taken into account in both Isothermal and temperature programmed experime
ISSN:0032-3888
DOI:10.1002/pen.760290506
出版商:Society of Plastics Engineers
年代:1989
数据来源: WILEY
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6. |
Kinetic studies of a composite thermoset cure reaction—application in pultrusion simulations |
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Polymer Engineering&Science,
Volume 29,
Issue 5,
1989,
Page 302-307
Hendra Ng,
Ica Manas‐Zloczower,
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PDF (520KB)
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摘要:
AbstractA mechanistic kinetic model based on the concept of free radical polymerization and corrected for diffusion controlled reactions was used to describe the curing behavior of an unsaturated polyester resin. Kinetic parameters for the model were obtained from dynamic differential scanning calorimetry (DSC) scans using a multiple regression technique. The presence of kaolinite or fiber glass in the system does not affect the progression of the reaction. The results obtained from the kinetic studies were used to simulate the influence of system composition on temperature and conversion profiles inside a pultrusion die. The results of the simulations show that kaolinite and fiber glass act as heat sinks for the composite system reducing the peak exotherm and delaying curing progression.
ISSN:0032-3888
DOI:10.1002/pen.760290507
出版商:Society of Plastics Engineers
年代:1989
数据来源: WILEY
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7. |
Monitoring cure in sheet molding compound processing |
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Polymer Engineering&Science,
Volume 29,
Issue 5,
1989,
Page 308-314
J. M. Castro,
E. J. Straus,
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PDF (583KB)
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摘要:
AbstractDuring the sheet molding compound (SMC) compression molding process, a premeasured polymer charge is placed between the heated halves of a mold which are then brought together to squeeze the polymer and fill the mold, after which pressure is maintained while the part cures. The cure stage constitutes the larger part of the molding cycle and thus affords the largest potential for cycle time reduction. In general, cure times in SMC processing are set longer than necessary, since the inherent material and process variation make it difficult to predict cure times with more than 10 to 20% accuracy. Accurate methods to detect the end of cure would be very beneficial and would permit opening the mold as soon as the material has cured, avoiding unnecessary waste of time. In this paper, several techniques that show promise for monitoring the state of cure are reviewed and experimental results given. Their relative advantages and accuracies are compared. In particular, the use of linear variable displacement transducers, pressure transducers, and thermocouples is discussed. We also show how the measurements compare to theoretical predictions of the state of cure.
ISSN:0032-3888
DOI:10.1002/pen.760290508
出版商:Society of Plastics Engineers
年代:1989
数据来源: WILEY
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8. |
Analysis of the Dielectric Response of Thermosets During Isothermal and Nonisothermal Cure |
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Polymer Engineering&Science,
Volume 29,
Issue 5,
1989,
Page 315-324
Kirk A. Nass,
James C. Seferis,
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PDF (867KB)
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摘要:
AbstractUsing dielectric techniques to monitor thermoset properties on‐line during processing requires a mathematical relationship between the experimentally obtained signals and the physical state of the polymer. Such a relationship accounting for the dielectric response during both isothermal and dynamic cure experiments is developed in this study. Ionic conductivity changes with cure were described using the Keinle‐Race expression, while an approach taken by Lane, Bachmann, and Seferis for modeling dipolar relaxation during isothermal cure was extended to nonisothermal cure conditions. Both of these approaches were combined in this study, providing a complete description of the dielectric changes occurring in thermosetting systems resulting from cure. Experimental results for a model epoxy/amine system were predicted with the developed methodology for isothermal cure at 140°C, 150°C, 160°C, and 170°C and cure under dynamic heating conditions at 1°C pe
ISSN:0032-3888
DOI:10.1002/pen.760290509
出版商:Society of Plastics Engineers
年代:1989
数据来源: WILEY
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9. |
Dielectric analysis of the cure of thermosetting epoxy/amine systems |
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Polymer Engineering&Science,
Volume 29,
Issue 5,
1989,
Page 325-328
Sue Ann Bidstrup,
Norman F. Sheppard,
Stephen D. Senturia,
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PDF (391KB)
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摘要:
AbstractA low molecular weight epoxy resin is cured isothermally with an aromatic amine hardener, and the dielectric properties are measured as a function of the frequency, reaction time, and cure temperature. At specific stages in the cure, small samples from the reacting mixture are quenched and subsequently analyzed for the glass transition temperature and epoxy group conversion by differential scanning calorimetry. In this manner, the change In dielectric properties can be directly correlated with the network structure. The ionic conductivity is modeled as a function of the cure temperature and the cure‐dependent glass transition temperature using a Williams‐Landel‐Ferry (WLF) relation. Combining this WLF relation with the DiBenedetto equation, a comprehensive model relating conductivity with the extent of reaction and cure temperature has been deve
ISSN:0032-3888
DOI:10.1002/pen.760290510
出版商:Society of Plastics Engineers
年代:1989
数据来源: WILEY
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10. |
Viscosity modeling during epoxy resin cure |
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Polymer Engineering&Science,
Volume 29,
Issue 5,
1989,
Page 329-333
George Schmitt,
John Wiley,
Jeffrey Gotro,
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PDF (468KB)
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摘要:
AbstractA model is presented that describes the changing melt viscosity of an epoxy laminating resin during its cure. The model incorporates chemical as well as physical factors. The predictions of the model are compared to experimental data using resin cured at several rates of heat‐rise, and at a fixed heat‐rise profile using resin preadvanced to different extents of reaction. Agreement is good, particularly at rapid heat‐rise rates, typical of those used in produ
ISSN:0032-3888
DOI:10.1002/pen.760290511
出版商:Society of Plastics Engineers
年代:1989
数据来源: WILEY
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