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1. |
Sodium nitrite as an inhibitor against the attack of sea water on steel. Part I. The influence of sodium nitrite on the area and intensity of attack |
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Journal of the Society of Chemical Industry,
Volume 68,
Issue 6,
1949,
Page 165-168
By D. Wyllie,
G. C. N. Cheesman,
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摘要:
AbstractThe prevention by sodium nitrite of the attack of sea water on steel has been studied in two ways.(a) Observation of the extent and nature of corrosion of mild steel specimens partially immersed in sea water containing nitrite.(b) Measurement of the corrosion currents using a divided cell.The appearance of a widespread brown discolouration on the steel at the higher nitrate concentrations is discussed and a catalytic mechanism is suggested for the inhibiting action of nitrite.The effect of mixing phosphates and nitrite is reported.
ISSN:0368-4075
DOI:10.1002/jctb.5000680601
出版商:John Wiley&Sons, Ltd
年代:1949
数据来源: WILEY
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2. |
New methods for the routine gravimetric analysis of boiler scales and deposits containing phosphate |
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Journal of the Society of Chemical Industry,
Volume 68,
Issue 6,
1949,
Page 168-171
J. E. Edwards,
C. P. Alcock,
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摘要:
AbstractMethods are described for the gravimetric determination of Calcium, Iron, Aluminium and Magnesium in the presence of Phosphate, without the removal of the phosphate.
ISSN:0368-4075
DOI:10.1002/jctb.5000680602
出版商:John Wiley&Sons, Ltd
年代:1949
数据来源: WILEY
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3. |
The practical problems of corrosion. Part XII. The influence of corrosion on the thermal deposition of calcium carbonate |
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Journal of the Society of Chemical Industry,
Volume 68,
Issue 6,
1949,
Page 171-173
J. N. Wanklyn,
U. R. Evans,
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摘要:
AbstractSteel specimens partly immersed in calcium bicarbonate solution develop a white band of calcium carbonate, the cathodic product, along the water‐line. When subsequently the surface is more deeply immersed in fresh bicarbonate solution, and heat conveyed to the liquid through the steel, the distribution of the calcium carbonate thrown out by thermal decomposition is almost unrelated to that of the calcium carbonate produced in the previous corrosion stage. Under the experimental conditions, the corrosion product contained both calcite and aragonite, and the thermal deposit only aragonit
ISSN:0368-4075
DOI:10.1002/jctb.5000680603
出版商:John Wiley&Sons, Ltd
年代:1949
数据来源: WILEY
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4. |
The effect of ventilation in moisture testing ovens |
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Journal of the Society of Chemical Industry,
Volume 68,
Issue 6,
1949,
Page 174-175
W. G. Iles,
C. F. Sharman,
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摘要:
AbstractDuring a study of the effect of ventilation rate on the loss of weight obtained in a standard moisture testing oven, apparently anomalous results have brought to light a “steaming effect” which can seriously vitiate moisture determinations upon biological material if ventilation with dry air is inadequate. Reference is made to an industrial oven developed as a result of this w
ISSN:0368-4075
DOI:10.1002/jctb.5000680604
出版商:John Wiley&Sons, Ltd
年代:1949
数据来源: WILEY
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5. |
The rapid determination of free acid and water‐soluble phosphate in calcium superphosphate |
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Journal of the Society of Chemical Industry,
Volume 68,
Issue 6,
1949,
Page 176-177
F. C. Guthrie,
J. T. Nance,
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摘要:
AbstractThe sample of superphosphate is extracted with water, and the solution titrated with carbonate‐free sodium hydroxide in two stages with appropriate indicators. The first stage gives the free acid, and the second stage an approximate result for the primary calcium phosphate, Ca(H2PO4)2. A suitable volume of the sodium hydroxide is then titrated with the superphosphate solution, giving a reading from which a more accurate value for the primary calcium phosphate can be obtained. The total soluble phosphate determined in this way agrees well with that found by gravimetric analysi
ISSN:0368-4075
DOI:10.1002/jctb.5000680605
出版商:John Wiley&Sons, Ltd
年代:1949
数据来源: WILEY
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6. |
Determination of coating weights on electrolytic tinplate |
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Journal of the Society of Chemical Industry,
Volume 68,
Issue 6,
1949,
Page 177-179
H. Liebmann,
J. W. Price,
S. H. Thompson,
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摘要:
AbstractCommercial electrolytic flow‐brightened tinplate of nominal 8 oz. per basis box coating weight is shown to contain a tin‐iron alloy at the interface of the tin and the steel base. The extent of this alloy layer has been determined and a suitable correction is suggested for coating weight determinations on this material by loss of weight in antimony chloride‐hydrochloric acid.This correction is an approximate one, and its value may be influenced by the nature ot the coating pr
ISSN:0368-4075
DOI:10.1002/jctb.5000680606
出版商:John Wiley&Sons, Ltd
年代:1949
数据来源: WILEY
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7. |
The explosive poly‐condensation of ethylene oxide |
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Journal of the Society of Chemical Industry,
Volume 68,
Issue 6,
1949,
Page 179-183
A. K. Gupta,
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ISSN:0368-4075
DOI:10.1002/jctb.5000680607
出版商:John Wiley&Sons, Ltd
年代:1949
数据来源: WILEY
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8. |
Seasonal variation in chemical composition of some of the littoral seaweeds common to scotland. Part II.Fucus serratus. Fucus Vesiculosus. Fucus spiralis and pelvetia canaliculata |
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Journal of the Society of Chemical Industry,
Volume 68,
Issue 6,
1949,
Page 183-189
W. A. P. Black,
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摘要:
AbstractIn previous communications,1,2,3the seasonal variation over a period of two years in the ash, iodine, crude protein, mannitol, laminarin and alginic acid contents of the Laminariaceae common to Scotland, has been reported, while in. a later paper,4the variations in the above constituents were given for the common littoral seaweedAscophyllum nodosum.The work has now been extended to include the other common littoral algae, namely,Fucus serratus, Fucus vesiculosus, Fucus spiralisandPelvetia canaliculataand the results have been correlated with the depth of immersion of these algae.
ISSN:0368-4075
DOI:10.1002/jctb.5000680608
出版商:John Wiley&Sons, Ltd
年代:1949
数据来源: WILEY
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9. |
The fungistatic properties ofp‐aminobenzoic acid and related compounds. Part II. Relative fungistatic activity |
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Journal of the Society of Chemical Industry,
Volume 68,
Issue 6,
1949,
Page 189-192
G. W. K. Cavill,
J. M. Vincent,
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摘要:
AbstractThe fungistatic activity of the methyl ton‐amylp‐amino‐benzoates and of theortho, metaandpara‐aminobenzoic acids and their methyl esters has been determined in the inhibition of the growth rate ofAspergillus niger, Byssochlamys fulvaandPenicillium roqueforti.An increased inhibition ofP. roquefortiin the presence of nitrate nitrogen,pHbeing maintained at about 3.5, has been noted and provision made to avoid this effect, as well as the complications mentioned in an earlier paper.The data are treated (i) on the basis of the reciprocal of concentration required for 50% inhibition (I50); (ii) as related to an adsorption phenomenon. On the basis of I50values there is a general increase in activity from the methyl to the amylp‐amino‐benzoate, also themetaisomer is markedly less effective than the correspondingortho‐orpara‐compound. The adsorption approach has proved of little use withP. roqucforti, but withB. fulvait seems to permit a useful analysis of the activity of the esters, particularly in terms of increasing biological adsorbability. The esters tested againstA. nigerdo not give the same clear cut picture. With bothB. fulvaandA. nigerthe low I50values of themetaisomer may be explained on the basis of the adso
ISSN:0368-4075
DOI:10.1002/jctb.5000680609
出版商:John Wiley&Sons, Ltd
年代:1949
数据来源: WILEY
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10. |
The analysis of mixtures of the stereoisomerides of hexachloro‐cyclohexane (benzene hexachloride) by means of infra‐red spectro‐scopy |
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Journal of the Society of Chemical Industry,
Volume 68,
Issue 6,
1949,
Page 192-195
L. W. Marrison,
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摘要:
AbstractA description is given of the rapid analysis of mixtures of the stereoisomers of hexachlorocyclohexane by means of infrared spectroscopy. The results obtained arc within 0·5 to 2·5% of the correct values. More than 100 samples per week can be analyse
ISSN:0368-4075
DOI:10.1002/jctb.5000680610
出版商:John Wiley&Sons, Ltd
年代:1949
数据来源: WILEY
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