|
1. |
Synthesis and surface characterization of a new multiblock copolymer based on poly(dimethylsiloxane) and aromatic polysulfone |
|
Macromolecular Rapid Communications,
Volume 18,
Issue 4,
1997,
Page 267-272
Giovanna Di Pasquale,
Angela La Rosa,
Antonino Mamo,
Preview
|
PDF (323KB)
|
|
摘要:
AbstractA new alternating block copolymer was synthesized from dihydroxy‐terminated poly‐(ether ketone sulfone) and bis(dimethylamino)‐terminated polydimethylsiloxane oligomers. The chemistry and the thermal properties are discussed. Surface chemical composition of films was analyzed by ESCA. Quantitative calculations showed a noticeable siloxane enrichment at the su
ISSN:1022-1336
DOI:10.1002/marc.1997.030180401
出版商:Hüthig&Wepf Verlag
年代:1997
数据来源: WILEY
|
2. |
Preparation of new poly(ester‐imide)s with cyanoazobenzene side chains generating optical phase‐conjugate signals |
|
Macromolecular Rapid Communications,
Volume 18,
Issue 4,
1997,
Page 273-279
Moriyuki Sato,
Kazuo Nakagawa,
Yuji Tada,
Seiji Ujiie,
Preview
|
PDF (315KB)
|
|
摘要:
AbstractNew semi‐rigid poly(ester‐imide)s with cyanoazobenzene side chains were prepared by melt polycondensation of a diethyl isophthalate derivative of cyanoazobenzene withN,N′‐dihexanols of five aromatic diimides in the presence of zinc acetate. Differential scanning calorimetry (DSC) measurements and polarizing microscope observations demonstrated that the polymers have glass transitions (Tg) between 46 and 93°C and show no liquid crystalline (LC) properties. All poly(ester‐imide)s generated optical phase‐conjugate (PC) signals at high reflectivity by degenerate four‐wave mixing (DFWM) at low p
ISSN:1022-1336
DOI:10.1002/marc.1997.030180402
出版商:Hüthig&Wepf Verlag
年代:1997
数据来源: WILEY
|
3. |
New metallomesogenic polymers built by self‐assembly of non‐mesomorphic stilbazole dimers and CF3SO3Ag through coordination bonds |
|
Macromolecular Rapid Communications,
Volume 18,
Issue 4,
1997,
Page 281-286
Hideyuki Kihara,
Takashi Kato,
Toshiyuki Uryu,
Preview
|
PDF (468KB)
|
|
摘要:
AbstractSupramolecular liquid‐crystalline main‐chain polymers have been obtained by self‐assembly of non‐mesomorphic bifunctional ligands and a transition metal ion. Stibazole dimers, bis[2‐(2‐{4‐[2‐(4‐pyridyl)vinyl]phenoxy}ethoxy)ethyl]ether(1)and 1,2‐bis[2‐(2‐{4‐[2‐(4‐pyridyl)vinyl]phenoxy}ethoxy)ethoxy]benzene(2)have been synthesized and complexed with silver trifluoromethanesulfonate (CF3SO3Ag). The metallomesogenic polymeric complexes formed by coordination bonds between the pyridyl groups of the stilbazole dimers and the silv
ISSN:1022-1336
DOI:10.1002/marc.1997.030180403
出版商:Hüthig&Wepf Verlag
年代:1997
数据来源: WILEY
|
4. |
Polyelectrolyte‐surfactant complexes containing photolabile diazosulfonate chromophores |
|
Macromolecular Rapid Communications,
Volume 18,
Issue 4,
1997,
Page 287-294
Markus Antonietti,
Rimantas Kublickas,
Oskar Nuyken,
Brigitte Voit,
Preview
|
PDF (415KB)
|
|
摘要:
AbstractLow‐molar‐mass surfactants (S) and polyelectrolytes (PE) containing diazosulfonate chromophores which are photo‐labile and electrically charged were used for the formation of polyelectrolyte/surfactant complexes (PESC) in combination with commonly used polyelectrolytes and surfactants. The stable complexes are no longer water‐soluble and were characterized by means of nuclear magnetic resonance spectroscopy and in some cases by means of gel‐permeation chromatography measurements. Complexes with a 1 : 1 stoichiomctry with respect to charge are formed. Ultraviolet irradiation of the photo‐labile PESC resulted in the loss of the ionic i
ISSN:1022-1336
DOI:10.1002/marc.1997.030180404
出版商:Hüthig&Wepf Verlag
年代:1997
数据来源: WILEY
|
5. |
Amphiphilic derivatives of poly(acrylic acid) as stabilizer in emulsion polymerisation |
|
Macromolecular Rapid Communications,
Volume 18,
Issue 4,
1997,
Page 295-302
Markus Antonietti,
Markus C. Weißenberger,
Preview
|
PDF (383KB)
|
|
摘要:
AbstractPoly(acrylic acid)s of various molecular weights and different degree of hydrophobic modification have been synthesized by a polymer analogous reaction with tetradecylamine or copolymerization with styrene. Testing these amphiphilic polymers as stabilizers for the emulsion polymerization of styrene reveals that well stabilized latices are obtained within a certain range of molecular weight and hydrophobicity. As an example, the addition of 1 wt.‐% polymer with respect to the monomer allows the synthesis of polystyrene latices with a radius of about 100 nm in the absence of ionic initiators or polar comonomer
ISSN:1022-1336
DOI:10.1002/marc.1997.030180405
出版商:Hüthig&Wepf Verlag
年代:1997
数据来源: WILEY
|
6. |
Polymerization ofN‐(2,3,4,5,6‐pentafluorophenyl)‐maleimide |
|
Macromolecular Rapid Communications,
Volume 18,
Issue 4,
1997,
Page 303-311
Tokio Hagiwara,
Naoyuki Kawashima,
Hiroshi Hamana,
Tadashi Narita,
Preview
|
PDF (412KB)
|
|
摘要:
AbstractA novel fluorine‐containing polymer, poly[N‐(2,3,4,5,6‐pentafluorophenyl)maleimide], was prepared by the anionic polymerization ofN‐(2,3,4,5,6‐pentafluorophenyl)maleimide (PFPMI). Anionic polymerization with alkali metaltert‐butoxides gave poly(PFPMI) in 14–32% yield. Phenyllithium andsec‐butyllithium also afforded poly(PFPMI). No polymer was obtained with a radical initiator such as 2,2′‐azoisobutyronitrile. The polymerization took place only via the vinylene group of PFPMI and no appreciable side‐reaction occurred. The obtained poly(PFPMI) shows unimodal molecular weight distribution and begins
ISSN:1022-1336
DOI:10.1002/marc.1997.030180406
出版商:Hüthig&Wepf Verlag
年代:1997
数据来源: WILEY
|
7. |
Reversible local melting in polymer crystals |
|
Macromolecular Rapid Communications,
Volume 18,
Issue 4,
1997,
Page 313-318
Iwao Okazaki,
Bernhard Wunderlich,
Preview
|
PDF (291KB)
|
|
摘要:
AbstractThe melting of poly(ethylene terephthalate) is analyzed by quasi‐isothermal, temperature‐modulated differential scanning calorimetry. The measurement is done by sinusoidally changing the temperature in the melting range (± 1.0 K). In the melting range a small portion of the sample melts reversibly. This observation is taken as a direct observation of the reversibility of melting of specific macromolecules as long as they are melting only partially and need no molecular nucleation for recrystalliza
ISSN:1022-1336
DOI:10.1002/marc.1997.030180407
出版商:Hüthig&Wepf Verlag
年代:1997
数据来源: WILEY
|
8. |
Gas phase polymerization of ethylene with a silica‐supported metallocene catalyst: influence of temperature on deactivation |
|
Macromolecular Rapid Communications,
Volume 18,
Issue 4,
1997,
Page 319-324
Peter Roos,
Gerben B. Meier,
Job Jan C. Samson,
Günter Weickert,
K. Roel Westerterp,
Preview
|
PDF (279KB)
|
|
摘要:
AbstractEthylene was polymerized at 5 bar in a stirred powder bed reactor with silica supportedrac‐Me2Si[Ind]2ZrCl2/methylaluminoxane (MAO) at temperatures between 40°C and 80°C using NaCl as support bed and triethylaluminium (TEA) as a scavenger for impurities. For this fixed recipe and a given charge of catalyst. the average catalyst activity is reproducible within 10% for low temperatures. The polymerization rate and the rate of deactivation increase with increasing temperature. The deactivation could be modeled using a first order dependence with respect to the polymerization r
ISSN:1022-1336
DOI:10.1002/marc.1997.030180408
出版商:Hüthig&Wepf Verlag
年代:1997
数据来源: WILEY
|
9. |
Intermolecular chain transfer to polymer with chain scission: general treatment and determination ofkp/ktrinL,L‐lactide polymerization |
|
Macromolecular Rapid Communications,
Volume 18,
Issue 4,
1997,
Page 325-333
Jolanta Baran,
Andrzej Duda,
Adam Kowalski,
Ryszard Szymanski,
Stanislaw Penczek,
Preview
|
PDF (445KB)
|
|
摘要:
AbstractA general kinetic treatment of the system with intermolecular chain transfer followed by fast reinitiation is given. It leads to the broadening of the molecular weight distribution (MWD), the number of growing chains being invariable. Thus, this system can be considered as a special case of living polymerization. A general method has been elaborated allowing the determination of the ratio of the rate constant of propagation (kp) to the rate constant of the bimolecular transfer (k(2)tr) from the dependence of the MWD on monomer conversion. Numerical values ofkp/k(2)trequal to ≈ 102and 25 were thus determined for the polymerization ofL,L‐lactide (L,L‐dilactide) initiated with aluminium tris(isopropoxide) trimer ({Al(OiPr)3}3) and tributyltin ethoxide (nBu3SnOEt), respect
ISSN:1022-1336
DOI:10.1002/marc.1997.030180409
出版商:Hüthig&Wepf Verlag
年代:1997
数据来源: WILEY
|
10. |
Alternating terpolymerization of three non‐homopolymerizable monomers |
|
Macromolecular Rapid Communications,
Volume 18,
Issue 4,
1997,
Page 335-342
Dietrich Braun,
Matthias Schacht,
Hartmut Elsässer,
Ferenc Tüdős,
Preview
|
PDF (361KB)
|
|
摘要:
AbstractThe free‐radical terpolymerization of maleic anhydride (MSA), isobutyl vinyl ether (VIBE) and anethol (ANE) at 60°C is described. These three monomers do not homopolymerize under the conditions used. Binary copolymers are only obtained from MSA and one of the two investigated donor monomers, whereas the binary copolymerization of VIBE with ANE is not possible. In all terpolymers from these three non‐homopolymerizable monomers the MSA content amounts to about 50 mol‐%; VIBE is about twice as reactive as ANE. The terpolymerization can formally also be described under the assumption that two binary complexes (MSA/ANE (I) and MSA/VIBE (II)) are copolymerized. For this case the reactivity ratiosrI= 0,9 andrII= 1,7 are ob
ISSN:1022-1336
DOI:10.1002/marc.1997.030180410
出版商:Hüthig&Wepf Verlag
年代:1997
数据来源: WILEY
|
|