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91. |
Zirconium Phosphonate Multilayers of Organic Redox Couples on Nanocrystalline TiO2Semiconductor Electrode |
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Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals,
Volume 316,
Issue 1,
1998,
Page 401-406
MyungSoon Lee,
HyunKwan Shim,
YeongIl Kim,
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摘要:
New type of surface modification of redox-couple multilayers on nanoporous TiO2film has been demonstrated. N,N′-bis(ethylphosphonic acid)-4,4′-bipyridinium chloride(VP) and N,N′-bis(ethyl dihydrogen phosphate)-3,4,9,10-perylene bis(dicarboximide)(EPPI) were directly coordinated at surface defect site Ti4+of nanoporous TiO2film electrode. The sequential adsorption by alternating treatment of ZrOCl2and VP or EPPI allows building up zirconium phosphonate multilayers of the redox couples. Cyclic voltammetry and UV-visible absorption measurement have shown the systematic layer-by-layer growing of the multilayers and the heterogeneous electron-transfer from TiO2conduction band to the redox couples multilayers. The estimated average amount of the redox couples in each layer on the electrode was about 1.0 × 10−11mole/cm2which is in agreement with the reported density of states assigned to surface Ti4+sites.
ISSN:1058-725X
DOI:10.1080/10587259808044537
出版商:Taylor & Francis Group
年代:1998
数据来源: Taylor
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92. |
Preparations of Lipid LB Films and their Applications to Olfactory Sensor |
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Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals,
Volume 316,
Issue 1,
1998,
Page 407-410
Su-An Choi,
Young-Jin Lee,
Yong-Keun Chang,
Jong-Duk Kim,
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摘要:
Nine different kinds of chemical vapors were identified by the response characteristics of quartz crystal microbalance(QCM) coated with lipid Langmuir-Blodgett(LB) films to the chemical vapors as the basic olfactory sensing system.
ISSN:1058-725X
DOI:10.1080/10587259808044538
出版商:Taylor & Francis Group
年代:1998
数据来源: Taylor
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93. |
Au Colloid Formation in Polysilane/Au Layered Film and its Application as Novel Optical Recording Media |
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Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals,
Volume 316,
Issue 1,
1998,
Page 411-414
Norio Nagayama,
Tomohiro Maeda,
Yoshiaki Sakurai,
Masaaki Yokoyama,
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摘要:
Vacuum deposited gold thin layer on a ultraviolet (UV) light pre-exposed polysilanc film undergoes colloidal gold formation by heating. This process was found to accompany the degradation of polysilane by catalytic oxidation due to the colloidal gold formed. Incorporating a titanyl phthalocyanine (TiOPc) pigment layer as a photon-thermal energy conversion layer in-between polysilane film and substrate, we have succeeded in demonstrating experimentally the possible application of such phenomenon to a new optical recording system.
ISSN:1058-725X
DOI:10.1080/10587259808044539
出版商:Taylor & Francis Group
年代:1998
数据来源: Taylor
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94. |
Guest Editor'S Preface |
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Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals,
Volume 316,
Issue 1,
1998,
Page -
Nakjoong Kim,
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摘要:
Korea-Japan Joint Forum (KJF), an annual bilateral joint forum, has been successively organized since 1990. The objectives of KJF are to promote our research activities through sharing the most recent information, discussion of mutual interests between two countries on the field of advanced organic materials.
ISSN:1058-725X
DOI:10.1080/10587259808044446
出版商:Taylor & Francis Group
年代:1998
数据来源: Taylor
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