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1. |
Detecting and avoiding unstable operation of autothermal reactors |
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AIChE Journal,
Volume 35,
Issue 6,
1989,
Page 881-890
Paul H. Gusciora,
Alan S. Foss,
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摘要:
AbstractAn on‐line procedure is developed that uses estimates of the dominant eigenvalues of a reactor‐exchanger system to detect impending unstable operating behavior. In the event reactor stability is threatened, changes are made in the reactor's nominal operating state through a procedure that ensures the attainment of an accessment is made through estimation of closed‐loop eigenvalues derived from a physically‐based dynamic model. The guiding of the reactor to safe and stable conditions is carried out through a multiloop control system that receives optimal process setpoints found from an interative search. Experiments were made on a laboratory autothermal reactor system to assess the correspondence of the predicted and observed degrees of reactor st
ISSN:0001-1541
DOI:10.1002/aic.690350602
出版商:American Institute of Chemical Engineers
年代:1989
数据来源: WILEY
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2. |
Feedforward and feedback control of a solution copolymerization reactor |
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AIChE Journal,
Volume 35,
Issue 6,
1989,
Page 891-907
John P. Congalidis,
John R. Richards,
W. Harmon Ray,
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摘要:
AbstractA control system is designed for a copolymerization reactor using a combination of feedforward, ratio, and feedback control to regulate polymer production rate, copolymer composition, molecular weight, and reactor temperature. The solution copolymerization of methyl methacrylate and vinyl acetate in a continuous stirred tank reactor is used as an illustrative example with the kinetic parameters and reactor operating conditions obtained from the literature. The process includes equipment to recycle unreacted monomers and solvent. The recycle stream introduces disturbances to the reactor feed, which perturb the polymer properties. A feedforward control strategy is proposed to counter these disturbances, and its effectiveness is demonstrated using the model. The mathematical model is used to investigate input/output control pairings in order to identify the fundamental nature of the solution copolymerization control problem and to determine the best control system structure. The combined feedforward/feedback strategy is tested on a nonlinear model of the process for set point changes and compensation of unmeasured reactor disturbances. The performance of the control system design was quite good, and such designs have been found successful in plant operations.
ISSN:0001-1541
DOI:10.1002/aic.690350603
出版商:American Institute of Chemical Engineers
年代:1989
数据来源: WILEY
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3. |
Porosity distributions in a fluidized bed with an immersed obstacle |
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AIChE Journal,
Volume 35,
Issue 6,
1989,
Page 908-922
J. X. Bouillard,
R. W. Lyczkowski,
D. Gidaspow,
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摘要:
AbstractErosion in bubbling fluidized‐bed combustors is a serious issue that may affect their reliability and economics. Available evidence suggests that the key to understanding this erosion is detailed knowledge of the coupled and complex phenomena of solids circulation and bubble motion. A thin transparent “two‐dimensional” rectangular fluidized bed with an obstacle served as a rough model for a fluidized‐bed combustor. This model was studied experimentally and computationally using two hydrodynamic equation sets. The computed hydrodynamic results agree reasonably well with experimental data. Bubble frequencies and sizes compare well with those obtained from analyzing a high‐speed motion picture frame‐by‐frame. Time‐averaged porosities computed from both models agree with time‐averaged porosity distributions measured with a gamma‐ray densitometer. The principal diferences between the data and the computations in this paper are due to asymmetries present in the experiment and to the simplified solids rheology used in th
ISSN:0001-1541
DOI:10.1002/aic.690350604
出版商:American Institute of Chemical Engineers
年代:1989
数据来源: WILEY
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4. |
Controller design for integrating and runaway processes involving time delay |
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AIChE Journal,
Volume 35,
Issue 6,
1989,
Page 923-930
Stanley B. Quinn,
C. K. Sanathanan,
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摘要:
AbstractThis paper presents an efficient method for the design of controllers for integrating and runaway processes. The method is based on model matching in the frequency domain. The presence of open‐loop instability as well as pure time delay in the process models make the design task challenging for these classes of processes.The goal is to achieve low‐order, easily implementable cascade controllers in a unity‐output‐feedback configuration. It is shown that the central problem is in the selection of appropriate reference models. Several key constraints are developed which relate a given process model to a class of reference models for achieving total stability. Typical design examples are presented to clearly illustrate the various mathematical tec
ISSN:0001-1541
DOI:10.1002/aic.690350605
出版商:American Institute of Chemical Engineers
年代:1989
数据来源: WILEY
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5. |
Holdup and interfacial area measurements using dynamic gas disengagement |
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AIChE Journal,
Volume 35,
Issue 6,
1989,
Page 931-942
Snehal A. Patel,
James G. Daly,
Dragomir B. Bukur,
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摘要:
AbstractThe dynamic gas disengagement technique is discussed comprehensively in this paper. Also outlined is the procedure for estimating holdup structures and bubble rise velocities in a bubble column, which is extended to include the methodology for estimating the Sauter mean bubble diameter and therefore the specific gas‐liquid interfacial area. The error limits for the estimated quantities are established using two extreme cases to describe the disengagement process: constant rate disengagement and interactive disengagement of bubbles. The analysis is done assuming a bimodal bubble size distribution; however, generalized equations for a multimodal bubble size distribution are also presented. Sensitivity of results to the two cases is illustrated using results obtained from experiments conducted with the air‐tap water system in two bubble columns (0.05 and 0.23 m in diameter, 3 m tall). Sauter mean bubble diameters and specific interfacial areas estimated using the two approaches provide lower and upper limits for values reported in the literat
ISSN:0001-1541
DOI:10.1002/aic.690350606
出版商:American Institute of Chemical Engineers
年代:1989
数据来源: WILEY
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6. |
Causality‐based failure‐driven learning in diagnostic expert systems |
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AIChE Journal,
Volume 35,
Issue 6,
1989,
Page 943-950
Steven H. Rich,
Venkat Venkatasubramanian,
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摘要:
AbstractIt has been recognized that a diagnostic expert system's ability to learn from past experience will improve its diagnostic efficiency as well as make it acquire new heuristics. In this paper, we propose a failure‐driven learning scheme by which the expert system automatically updates its compiled knowledge by acquiring new heuristics or refining existing heuristics. A heuristic is refined if it hypothesizes the wrong causal origin during a diagnosis. Using its deep‐level knowledge of the process, the expert system draws inductive inferences from causal models to determine why the hypothesis proposed by the heuristic is inconsistent with the current state of the process. The refinement limits the applicability of the heuristic and prevents it from firing if a similar situation were to subsequently ar
ISSN:0001-1541
DOI:10.1002/aic.690350607
出版商:American Institute of Chemical Engineers
年代:1989
数据来源: WILEY
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7. |
Desorption processes: Supercritical fluid regeneration of activated carbon |
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AIChE Journal,
Volume 35,
Issue 6,
1989,
Page 951-958
F. Recasens,
B. J. McCoy,
J. M. Smith,
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摘要:
AbstractModels are developed for isothermal desorption in a fixed bed of adsorbent particles. While more general models require numerical solution of the governing equations, two practically important cases have analytical solutions: (1) an equilibrium desorption model where the rate of desorption is controlled by external and intraparticle mass transfer; and (2) a kinetic model where external and intraparticle mass transfer and a first‐order irreversible desorption step control the overall process.Recent experimental data (Tan and Liou, 1988) for the desorption of ethyl acetate from activated carbon with supercritical carbon dioxide are found to fit the local‐equilibrium model. Data for the effect of temperature on fractions desorbed indicate a reversal of the temperature dependence of the adsorption isotherm as the supercritical pressure is increased. This phenomenon is analogous to the observed cross‐over region for the effect of temperature on the solubility of a solid at supercritical condi
ISSN:0001-1541
DOI:10.1002/aic.690350608
出版商:American Institute of Chemical Engineers
年代:1989
数据来源: WILEY
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8. |
Absorbed solution theory models for multicomponent adsorption equilibria |
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AIChE Journal,
Volume 35,
Issue 6,
1989,
Page 959-966
Giuseppe Gamba,
Renato Rota,
Giuseppe Storti,
Sergio Carra,
Massimo Morbidelli,
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摘要:
AbstractA new approach is developed for applying ideal and real adsorbed solution theory models to the description of multicomponent adsorption equilibria at fixed pressure. This allows ignoring single‐component behavior in the Henry's law region,P→ O, but introduces new parameters that must be evaluated from binary equilibrium data. Comparisons with various sets of experimental data show that the new approach gives results as good as the classical one, but without requiring knowledge of the single component behavior in the Henry's law region; more over, it removes the sensitivity to the type of model adopted in fitting single‐component equilibrium
ISSN:0001-1541
DOI:10.1002/aic.690350609
出版商:American Institute of Chemical Engineers
年代:1989
数据来源: WILEY
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9. |
Simulation of microstructure/mechanism relationships in particle deposition |
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AIChE Journal,
Volume 35,
Issue 6,
1989,
Page 967-980
M. Tassopoulos,
J. A. O'Brien,
D. E. Rosner,
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摘要:
AbstractThe important connection between particulate deposit properties and deposition mechanism remains poorly understood and only scarcely studied. Accordingly, in this research, we develop a discrete stochastic model to simulate particulate deposition processes resulting from realistic combinations of deposition mechanisms. Particle motion is assumed to be determined by the superposition of a deterministic force that acts toward the collecting surface and a random force, which produces Brownian diffusion. We characterize the resulting deposit microstructure via porosity and pore size/area distribution, surface area; and we examine the evolution of these descriptors with time (number of particles deposited) for different deposition mechanisms. We also examine the effect of particle polydispersity, spatial orientation (for nonspherical particles), and mean‐free‐path on the resulting deposit struct
ISSN:0001-1541
DOI:10.1002/aic.690350610
出版商:American Institute of Chemical Engineers
年代:1989
数据来源: WILEY
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10. |
Experimental data for the crossover process in a model supercritical system |
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AIChE Journal,
Volume 35,
Issue 6,
1989,
Page 981-987
F. D. Kelley,
E. H. Chimowitz,
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摘要:
AbstractThis paper presents the experimental technique and data acquired in the evaluation of a separation process in the crossover region of a model supercritical fluid system consisting of benzoic acid, 1–10 decanediol, and carbon dioxide. The results show that by exploiting the crossover effect it is possible to obtain essentially pure benzoic acid (>99.5% purity) with a single temperature cycle. A number of other issues are also discussed including the tradeoff between yield and purity and the manner in which the process variables are specified, which involves the interplay of experiment and model calculation
ISSN:0001-1541
DOI:10.1002/aic.690350611
出版商:American Institute of Chemical Engineers
年代:1989
数据来源: WILEY
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