1. |
Adsorption of nitric oxide in aqueous slurries of activated carbon: Transport rates by moment analysis of dynamic data |
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AIChE Journal,
Volume 22,
Issue 6,
1976,
Page 961-970
Hiroo Niiyama,
J. M. Smith,
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摘要:
AbstractMoment analysis of input‐response data for three‐phase slurry reactors is shown to be useful for detrmining mass trasnport rate coefficients. Data for the nitric oxide‐water activated carbon system indicated that bubble‐to‐liquid transport, intraparticle diffusion, and the adsorption step could all influence the adsorption rate for high concentrations of carbon
ISSN:0001-1541
DOI:10.1002/aic.690220603
出版商:American Institute of Chemical Engineers
年代:1976
数据来源: WILEY
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2. |
Separation sequence synthesis by a predictor based ordered search |
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AIChE Journal,
Volume 22,
Issue 6,
1976,
Page 970-979
Alejandro Gomez M.,
J. D. Seader,
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摘要:
AbstractA predictor based ordered search procedure is used to scan the graph representing all possible separation sequences for a given multicomponent separation process. The algorithmic procedure is expedited by utilizing an heuristic cost function to obtain lower bound estimates of the cost of separators not yet designed. Considerable reduction in search space occurs. Optimal and near optimal sequences are readily generated.
ISSN:0001-1541
DOI:10.1002/aic.690220604
出版商:American Institute of Chemical Engineers
年代:1976
数据来源: WILEY
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3. |
Application of the limiting current method to mass transfer in packed beds at very low reynolds numbers |
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AIChE Journal,
Volume 22,
Issue 6,
1976,
Page 979-984
Peter W. Appel,
John Newman,
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摘要:
AbstractThe limiting current technique is used to obtain mass transfer coefficients at very low Reynolds numbers (Re<0.1) in a packed bed consisting of stainless steel spheres. The data show that forRe<0.015, the Nusselt numbers are below those predicted by existing empirical correlations. The results are discussed in the light of some mathematical models for packed beds reported in the literature and show semiquantitative agreement with the values predicted by Sorensen and Stewart (1974a).
ISSN:0001-1541
DOI:10.1002/aic.690220605
出版商:American Institute of Chemical Engineers
年代:1976
数据来源: WILEY
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4. |
On the optimization by boundary control of tubular reactors with catalyst decay |
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AIChE Journal,
Volume 22,
Issue 6,
1976,
Page 985-989
Frans Gruyaert,
C. M. Crowe,
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摘要:
AbstractIn optimization problems dealing with catalytic reactors, where the catalyst deactivates slowly with time, it is common to assume a quasi steady state in the reaction and deactivation equations. Although the difference in reactor performance, for a given control policy, between the unsteady state reactor and its quasi steady state approximation is usually negligible, a very large difference can exist in the optimal control policy for the two models. For a single irreversible reaction, where the catalyst deactivation is dependent on conversion and where the control variable is the temperature of the fluid entering a tubular reactor, it is shown numerically that the performance of the reactor for a suboptimal control policy can be significantly superior to the optimal performance predicted from a quasi steady state model formulation.
ISSN:0001-1541
DOI:10.1002/aic.690220606
出版商:American Institute of Chemical Engineers
年代:1976
数据来源: WILEY
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5. |
The interfacial drag and the height of the wall layer in annular flows |
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AIChE Journal,
Volume 22,
Issue 6,
1976,
Page 990-1000
William H. Henstock,
Thomas J. Hanratty,
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摘要:
AbstractA method to predict the height of the wall layer and the interfacial drag in annular flow under conditions that the flow rate of the entrained liquid is known is developed from measurements on air‐water flow in circular tubes. Flow conditions are found to be characterized by a generalized Martinelli flow paramete
ISSN:0001-1541
DOI:10.1002/aic.690220607
出版商:American Institute of Chemical Engineers
年代:1976
数据来源: WILEY
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6. |
Mass transfer of dissolved gases through tubular membrane |
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AIChE Journal,
Volume 22,
Issue 6,
1976,
Page 1000-1006
Thomas E. Tang,
Sun‐Tak Hwang,
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摘要:
AbstractMass transfer characteristics are studied theoretically and experimentally for dissolved oxygen and carbon dioxide in fully developed laminar flow through a gas permeable membrane tubing. The gas transfer rate is correlated with the liquid flow rate and tubing size. Membrane resistance together with liquid phase resistance determine the overall mass transport rate.
ISSN:0001-1541
DOI:10.1002/aic.690220608
出版商:American Institute of Chemical Engineers
年代:1976
数据来源: WILEY
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7. |
Explaining solubilization kinetics |
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AIChE Journal,
Volume 22,
Issue 6,
1976,
Page 1006-1012
A. F. Chan,
D. Fennell Evans,
E. L. Cussler,
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摘要:
AbstractSolubilization rates of fatty acids in pure detergent solutions are controlled by mixed micelle desorption and diffusion. Solubilization rates in partially saturated detergent solutions also involve exchange of fatty acids between the solid and the solution. These conclusions depend on models like those used in gas‐solid catalysis and in tracer diffusio
ISSN:0001-1541
DOI:10.1002/aic.690220609
出版商:American Institute of Chemical Engineers
年代:1976
数据来源: WILEY
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8. |
An analysis of slow reactions in a porous particle |
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AIChE Journal,
Volume 22,
Issue 6,
1976,
Page 1012-1021
C. Y. Wen,
Nancy Tsai Wu,
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摘要:
AbstractA one‐parameter volume reaction model is developed by a simplified analytical approach to describe reaction of a gas and a consumble solid in a porous particle. In this model, a modified Thiele modulusMis introduced to take into account the effect of solid reactant depletion during the reaction.Experimental results of an isothermal carbon‐carbon dioxide reaction in the temperature range from 1 130° to 1 365°K under atmospheric pressure were analyzed by the working diagrams derived from this model. A satisfactory agreement between the experimental results and those predicted by the model indicated the applicability of this
ISSN:0001-1541
DOI:10.1002/aic.690220610
出版商:American Institute of Chemical Engineers
年代:1976
数据来源: WILEY
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9. |
The effect of flow maldistribution on conversion in a catalytic packed‐bed reactor. Part I. Analysis |
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AIChE Journal,
Volume 22,
Issue 6,
1976,
Page 1021-1027
Manoj Choudhary,
Julian Szekely,
Sol W. Weller,
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摘要:
AbstractThrough the statement of the vectorial form of the Ergun equation, combined with a differential component balance, a formulation was developed describing the velocity fields and reactant concentration profiles in an isothermal packed‐bed reactor in which the gas flow is nonuniform. This flow maldistribution was caused by both the preferential flow near the wall, inherent in most systems, and by the deliberate arrangement of the solid packing in the bed. The numerical solution of the governing equations showed that a nonuniform flow field had a very strong effect in distorting the concentration isopleths, particularly at intermediate conversion level
ISSN:0001-1541
DOI:10.1002/aic.690220611
出版商:American Institute of Chemical Engineers
年代:1976
数据来源: WILEY
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10. |
The effect of flow maldistribution on conversion in a catalytic packed‐bed reactor. Part II. Experimental studies |
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AIChE Journal,
Volume 22,
Issue 6,
1976,
Page 1027-1032
Manoj Choudhary,
Sol W. Weller,
Julian Szekely,
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摘要:
AbstractThe modeling equations formulated for a catalytic packed‐bed reactor with distributed resistance to flow have been applied to the alumina catalyzed isomerization of 1‐butene to cis‐ and trans‐2‐butene. Flow maldistribution was deliberately created in a 5.25 cm I.D. reactor by packing different radial sections with alumina particles of different size. Effluent gas composition, monitored by gas chromatography, was found to vary with radial position in a manner consistent with the modeling equations and with the reaction rate constant previously established in a mic
ISSN:0001-1541
DOI:10.1002/aic.690220612
出版商:American Institute of Chemical Engineers
年代:1976
数据来源: WILEY
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