摘要:

Salts containing thiazyl (SN+), dithionitronium (S2N+) and sulfur diimide (SN2-2) ions can be used as sources for these small sulfur-nitrogen units in synthetic studies. The highly reactive molecules sulfur nitride (SN) and dinitrogen sulfide (N=N=S) are known as transients in the gas phase, and the existence of anionic species such as the radical SN2- or dithionitrite (S2N-) has been deduced from electrochemical studies. The thionitroysl group (NS) is a versatile three-electron acceptor system in transition metal complexes; it is generally coordinated as a linear terminal ligand.

ISSN:0260-3594    

DOI:10.1080/02603598808072300

出版商:Taylor & Francis Group    

年代:1988

数据来源: Taylor

摘要:

A total of 14,000 organometallic compounds synthesized and characterized up to a few years ago are listed in the “Dictionary of Organometallic Chemistry,” while the properties and chemistry of these compounds are described on 8,500 printed pages of “Comprehensive Organometallic Chemistry” edited in 1984. Why has there been ever-increasing worldwide activity in organometallic chemistry since the days when ferrocene showed up in the literature? More importantly, what appear to be the future main lines of research and to which goals should we dedicate our efforts? This Comment,1based on a historical background, endeavors to exemplify the present status of organometallic chemistry within the spectrum of the neighboring disciplines of chemistry. By virtue of several examples of the author's scientific interests, one particular area of research will be discussed that has largely been neglected in organometallic chemistry up to the present.

ISSN:0260-3594    

DOI:10.1080/02603598808072301

出版商:Taylor & Francis Group    

年代:1988

数据来源: Taylor

摘要:

This is a scanned image of the original Editorial Board page(s) for this issue.

ISSN:0260-3594    

DOI:10.1080/02603598808072299

出版商:Taylor & Francis Group    

年代:1988

数据来源: Taylor