摘要:

Coordinated azido groups undergo a great variety of reactions and therefore exhibit an interesting synthetic potential. In most cases the azido group decomposes and transforms partially or completely to molecular nitrogen yielding new compounds with metal-nitrogen bonds or complexes with a reduced metal. The products can be nitrido, nitrene, or phosphoraniminato complexes with metal-nitrogen multiple bonds as well as nitrosyl, cyanato, chlorineamine and dinitrogen complexes. In other cases the complete azido group is involved in a cycloaddition reaction or a nitrene is inserted in a metal-metal or metal-ligand bond. Typical examples of the different types of reactions are discussed.

ISSN:0260-3594    

DOI:10.1080/02603598508072269

出版商:Taylor & Francis Group    

年代:1985

数据来源: Taylor

摘要:

The principles underlying correlations of charge transfer energies for related metal complexes are examined in light of data that have become available in recent years. As a consequence, the charge transfer absorption band of Co(CN)3-6at 50,600 cm−1is assigned to a σ(CN) → do*Co) transition.

ISSN:0260-3594    

DOI:10.1080/02603598508072270

出版商:Taylor & Francis Group    

年代:1985

数据来源: Taylor

摘要:

It is shown that the rates of intramolecular electron transfer for mixed-valence complexes in the solid state are not determined only by the electronic and vibronic coupling in the molecular complex. Lattice dynamics associated with the motion of ligands, solvate and counterions, which sometimes are manifested as phase transitions, frequently influence the electron-transfer rate.

ISSN:0260-3594    

DOI:10.1080/02603598508072271

出版商:Taylor & Francis Group    

年代:1985

数据来源: Taylor

摘要:

This is a scanned image of the original Editorial Board page(s) for this issue.

ISSN:0260-3594    

DOI:10.1080/02603598508072268

出版商:Taylor & Francis Group    

年代:1985

数据来源: Taylor