1. |
Molecular Dynamics of Binary Fluids in the Region of the Critical Mixing Point: II. The Static and Dynamic Behaviour |
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Physics and Chemistry of Liquids,
Volume 9,
Issue 4,
1980,
Page 265-284
Claus Hoheisel,
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摘要:
In this second part of our report we continue the description of our molecular dynamics (MD) investigations on partially miscible binary fluids near the critical mixing point.1Whereas our first article has reported the basic aspects of our attempt to simulate near-critical states, the present paper describes and discusses the entirely calculated results of our simulations.
ISSN:0031-9104
DOI:10.1080/00319108008084781
出版商:Taylor & Francis Group
年代:1980
数据来源: Taylor
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2. |
General Equations for the Equilibrium Shape of a Fluid Interface and for Its Angle of Contact with a Solid |
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Physics and Chemistry of Liquids,
Volume 9,
Issue 4,
1980,
Page 285-305
M.A. Fortes,
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摘要:
The classical equations of Young-Laplace (equilibrium shape of a fluid interface in a uniform gravitational field) and Young (angle of contact of the fluid interface with a solid) are generalized to take into account: (i) the presence of externally applied fields of any type; (ii) the variation of the interfacial tensions from point to point; (iii) the variation of the fluid interfacial tension with its orientation in space.
ISSN:0031-9104
DOI:10.1080/00319108008084782
出版商:Taylor & Francis Group
年代:1980
数据来源: Taylor
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3. |
Thermodynamic Properties of Liquid Na-TI |
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Physics and Chemistry of Liquids,
Volume 9,
Issue 4,
1980,
Page 307-321
P. Gray,
N.E. Cusack,
S. Tamaki,
Y. Tsuchiya,
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摘要:
New measurements of the free energy and entropy of mixing and association thermodynamic properties of liquid Na-TI alloys at three temlperatures are reported. A thermodynamic model is developed and fitted to these with success but the failure of the model to fit the properties of Na-Ga is reported. The problems involved in fitting thermodynamic models are discussed.
ISSN:0031-9104
DOI:10.1080/00319108008084783
出版商:Taylor & Francis Group
年代:1980
数据来源: Taylor
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4. |
On the Thermodynamics of Liquid Mixtures of Twon- Alkanes |
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Physics and Chemistry of Liquids,
Volume 9,
Issue 4,
1980,
Page 323-329
Ernst Liebermann,
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PDF (281KB)
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摘要:
The excess molar volumeVEof liquid mixtures of twon-alkane sis predicted essentially on the basis of the van der Waals model. The important feature of the treatment is thatVEmay be calculated from the respective desnsitis, isobaric expansivities and isothermal compressibilisties of the pure liquids, whereas data of solution properties need not be known. Neither any combining rules nor emprically adjusted parameters are used. Computed values are slightly less negative than the observed excess volumes, the average deviation being about 10%.
ISSN:0031-9104
DOI:10.1080/00319108008084784
出版商:Taylor & Francis Group
年代:1980
数据来源: Taylor
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