摘要:

The literature on the solubility of mercury and of the sparingly soluble salts of mercury (I) and mercury (II) in water and in aqueous electrolyte solutions has been reviewed. The solubility data have been compiled and evaluated. Recommended and tentative values of the solubilities are presented when warranted. Auxiliary thermodynamic data and crystallographic data useful in the interpretation of solubility data are given. An annotated bibliography on the solubility of some of the less common inorganic mercury compounds, with emphasis on the solubility literature published since 1950, is given.

ISSN:0047-2689    

DOI:10.1063/1.555732

出版商:AIP    

年代:1985

数据来源: AIP

摘要:

The available experimental data for vapor–liquid equilibria, heat of mixing, change in volume on mixing for liquid mixtures, and gas‐phasePVTmeasurements for nitrogen+methane have been reviewed and where possible evaluated for consistency. The derived properties chosen for analysis and correlation were liquid mixture excess Gibbs free energies, and Henry’s constants.

ISSN:0047-2689    

DOI:10.1063/1.555733

出版商:AIP    

年代:1985

数据来源: AIP

摘要:

This work provides a critical compilation of the homogeneous nucleation limits of liquids. Data for 90 pure substances and 28 mixtures have been compiled over a range of pressures, nucleation rates, and compositions. Detailed descriptions of the experimental methods used to obtain the included data are given to assess the accuracy of measured values. Criteria used to select the measurements included in the final listing are discussed.

ISSN:0047-2689    

DOI:10.1063/1.555734

出版商:AIP    

年代:1985

数据来源: AIP

摘要:

This article updates a ten‐year‐old review of this subject [J. Chem. Phys. Ref. Data4, 539 (1975)]. A survey of the electron affinity determinations for the elements up toZ=85 is presented, and based upon these data, a set of recommended electron affinities is established. Recent calculations of atomic electron affinities and the major semiempirical methods are discussed and compared with experiment. The experimental methods which yield electron binding energy data are described and intercompared. Fine structure splittings of these ions and excited state term energies are given.

ISSN:0047-2689    

DOI:10.1063/1.555735

出版商:AIP    

年代:1985

数据来源: AIP

摘要:

Energy level data are given for the atom and all positive ions of phosphorus (Z=15). These data have been critically compiled, mainly from published and unpublished material on measurements and analyses of the optical spectra. We have derived or recalculated the levels for a number of the ions. In addition to the level values in cm−1and the parity, theJvalue and the configuration and term assignments are listed if known. Leading percentages from the calculated eigenvectors are tabulated or quoted wherever available. Ionization energies are given for all spectra.

ISSN:0047-2689    

DOI:10.1063/1.555736

出版商:AIP    

年代:1985

数据来源: AIP

摘要:

The chemical thermodynamic properties of alkene isomer groups from C4H8to C6H12in the ideal gas phase have been calculated from 298.15 to 1000 K from tables of Stull, Westrum, and Sinke. In the absence of literature data on all isomers of higher isomer groups, the properties of isomers of C7H14to C8H16have been estimated using Benson group values. Equilibrium mole fractions within isomer groups have been calculated for the ideal gas state from 298.15 to 1000 K. For isomer group properties increments per carbon atom have been calculated to show the extent to which thermodynamic properties of higher isomer groups may be obtained by linear extrapolation. Values ofC○P,S°, &Dgr;fH°, and &Dgr;fG° are given for all species from C2H4to C8H16in joules for a standard state pressure of 1 bar.

ISSN:0047-2689    

DOI:10.1063/1.555737

出版商:AIP    

年代:1985

数据来源: AIP

摘要:

The chemical thermodynamic properties of alkylnaphthalene isomer groups for C10H8and C11H10in the ideal gas phase have been calculated from 298.15 to 1000 K from tables of Stull, Westrum, and Sinke. In the absence of literature data on all isomers of higher isomer groups, the properties of isomers of C12H12to C14H16have been calculated using Benson group values. A new Benson group value for the 1,8‐dimethyl steric hindrance has been calculated from recent experimental data. The increments in isomer group properties per carbon atom have been calculated to show the extent to which thermodynamic properties of higher isomer groups may be obtained by linear extrapolation. Equilibrium mole fractions within isomer groups have been calculated for the ideal gas state from 298.15 to 1000 K. Values ofC○p,S°, &Dgr;fH°, and &Dgr;fG° are given for all species from C10H8to C14H16with energy units of joules for a standard state pressure of 1 bar.

ISSN:0047-2689    

DOI:10.1063/1.555738

出版商:AIP    

年代:1985

数据来源: AIP