ISSN:0005-9021    

DOI:10.1002/bbpc.19600640102

出版商:Wiley‐VCH Verlag GmbH&Co. KGaA    

年代:1960

数据来源: WILEY

摘要:

AbstractThe rapid reaction method introduced in 1923 to study the reaction of oxygen with haemoglobin is discussed. Results on haemoglobin solutions are compared with those on suspensions of red blood corpuscles and the rate‐limiting effects of the various processes involved in the oxygenation of blood in the lungs determine

ISSN:0005-9021    

DOI:10.1002/bbpc.19600640103

出版商:Wiley‐VCH Verlag GmbH&Co. KGaA    

年代:1960

数据来源: WILEY

摘要:

AbstractThe reaction between haematin and globin is kinetically complex and takes place quite slowly. The rate is independent of the globin concentration. The reaction between carboxyhaem and globin is rapid (k= 7 · 107M−1sec−1) and second order. This high rate suggests that the combining site lies near the surface of the globin molecule. It is so great as to tax the method to the utmost: the reaction is among the most rapid to be studied by flow met

ISSN:0005-9021    

DOI:10.1002/bbpc.19600640104

出版商:Wiley‐VCH Verlag GmbH&Co. KGaA    

年代:1960

数据来源: WILEY

摘要:

AbstractThe mechanism of enzyme action presents a formidable and challenging problem to the chemist and has spurred the development of rapid reaction methods towards the maximum in sensitivity and time resolution, in order to meet the stringent requirements of enzyme reactions. In this paper we will emphasize the ways in which rapid flow techniques have allowed the study of enzyme reactions in living cells and in isolated enzyme systems with various types of physical methods, some of which are inherently insensitive and sluggish.

ISSN:0005-9021    

DOI:10.1002/bbpc.19600640105

出版商:Wiley‐VCH Verlag GmbH&Co. KGaA    

年代:1960

数据来源: WILEY

ISSN:0005-9021    

DOI:10.1002/bbpc.19600640106

出版商:Wiley‐VCH Verlag GmbH&Co. KGaA    

年代:1960

数据来源: WILEY

ISSN:0005-9021    

DOI:10.1002/bbpc.19600640107

出版商:Wiley‐VCH Verlag GmbH&Co. KGaA    

年代:1960

数据来源: WILEY

ISSN:0005-9021    

DOI:10.1002/bbpc.19600640108

出版商:Wiley‐VCH Verlag GmbH&Co. KGaA    

年代:1960

数据来源: WILEY

摘要:

AbstractThe polarographic currents controlled by chemical reactions being involved in the depolarization processes are discussed. A simplified theory of computing rate constants from polarographic data is given and concrete examples of some typical systems are presented.

ISSN:0005-9021    

DOI:10.1002/bbpc.19600640109

出版商:Wiley‐VCH Verlag GmbH&Co. KGaA    

年代:1960

数据来源: WILEY

摘要:

AbstractThe conditions of the reaction layer near the electrode surface caused by a rapid chemical reaction controlling the electrode process is discussed. The limits of the rate constants which can be obtained by polarographic kinetic currents are determined. The case is considered where the reaction layer is partially or completely in the diffusion part of the electrode double layer. Chemical reactions which control the electrode process without complicating influences are cited.

ISSN:0005-9021    

DOI:10.1002/bbpc.19600640110

出版商:Wiley‐VCH Verlag GmbH&Co. KGaA    

年代:1960

数据来源: WILEY

摘要:

AbstractThe effect of a (prior) chemical reaction step on the course of an electrode reaction is described and it is found that potentiostatic experiments are very suitable for the analysis of the process. The application of the method to the system [Cd(CN)4]2↰ [Cd(CN)3]−+ CN−is described. The results give an insight into the difficulties involved in the interpretation of rate constants which are obtained in this m

ISSN:0005-9021    

DOI:10.1002/bbpc.19600640111

出版商:Wiley‐VCH Verlag GmbH&Co. KGaA    

年代:1960

数据来源: WILEY