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| 11. |
New Observations on the Belousov‐Zhabotinskii Reaction. The Oscillating Reaction of Organic Gallic Acid and Potassium Bromate Catalyzed by 1,10‐o‐Phenanthroline‐Iron(II) Complex |
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Journal of the Chinese Chemical Society,
Volume 33,
Issue 1,
1986,
Page 91-94
Jing‐Jer Jwo,
Eng‐Fen Chang,
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摘要:
AbstractThe oscillating reaction involving organic gallic acid (GA), potassium bromate, and a metal ion complex has been reinvestigated. In contrast to other previous reports, this oscillating reaction is catalyzed by the [Fe(phen)n]2+ion (phen = 1,10‐o‐phenanthroline,n=1, 2, 3) rather than by the cerium ion. The characteristics of the oscillations depend on the temperature and on the concentrations of the potassium bromate, gallic acid, [Fe(phen)n]2+, and sulfuric acid. A cyclic voltammetric study indicates that the redox potential and the reversibility of the [Fe(phen)n]2+/3+couple play a major role in catalyzing this oscillating sys
ISSN:0009-4536
DOI:10.1002/jccs.198600011
出版商:WILEY‐VCH Verlag
年代:1986
数据来源: WILEY
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| 12. |
Preparation of Cis‐Enediones from Furans by Photooxidation |
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Journal of the Chinese Chemical Society,
Volume 33,
Issue 1,
1986,
Page 95-97
Yueh‐Hsiung Kuo,
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摘要:
AbstractPhotooxidation of furan derivatives followed by reduction with methyl sulfide affords cis‐enediones in excellent yield
ISSN:0009-4536
DOI:10.1002/jccs.198600012
出版商:WILEY‐VCH Verlag
年代:1986
数据来源: WILEY
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Volume 33 issue 1