1. |
Szilard‐Chalmers Reaction with Copper Chelates |
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Journal of the Chinese Chemical Society,
Volume 9,
Issue 4,
1962,
Page 205-219
Si Jung Yeh,
Moon‐Lung Yin,
Jing Liang Chou,
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摘要:
AbstractFour copper compounds, bis‐acetylacetone‐Cu(II) (A), bis‐dibenzoylmethane‐Cu(II) (B), acetylacetoneethylenediimine‐Cu(II) (C) and benzoylacetoneethylenediimimine‐Cu(II) (D) have been prepared and used as the targets in carrying out Szilard‐Chalmers process to investigate the feasibility for the enrichment of Cu‐64. Both solvent extraction method and re‐precipition method were used to separate the enriched Cu‐64. It was observed that no enrichment was brought about in the operations with compounds (A) and (B) under the condition studied. With compounds (C) and (D) however, enrichment factors of the order of 200–400 and 70–90, resp
ISSN:0009-4536
DOI:10.1002/jccs.196200023
出版商:WILEY‐VCH Verlag
年代:1962
数据来源: WILEY
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2. |
Determination of the Dissociation Constants of Rosolic Acid by Spectrography |
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Journal of the Chinese Chemical Society,
Volume 9,
Issue 4,
1962,
Page 220-229
Tsong‐Hsing Lin,
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摘要:
AbstractRosolic acid was found to exhibit an absorption maximum at 480 mμ which shifts toward longer wave‐lengths in alkaline solutions. Spectrophotometic observation on this absorption maximum was made, and the optical density vspH curve was found to pass through a minimum atpH=5.98. By using Thamer and Vaigt's method, the author was able to evaluate the dissociation constants of rosolic ac
ISSN:0009-4536
DOI:10.1002/jccs.196200024
出版商:WILEY‐VCH Verlag
年代:1962
数据来源: WILEY
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3. |
Photometric Studies of Bivalent Metal Chelates |
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Journal of the Chinese Chemical Society,
Volume 9,
Issue 4,
1962,
Page 230-248
Mei‐Wei Hwang,
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摘要:
AbstractThe phosphorescence Spectra of pure oxine and bivalent oxinates, namely, magnesium, calcium, manganese, cobalt, nickel, copper, zinc, cadmium and lead were studied at 77°K in rigid glass solution for the purpose of evaluating their phosphorescence efficiencies as related to the atomic number which permit qualitative deduction to be made in regard to the magnetic susceptibility and greater orbital interaction with atoms of higher atomic number (Z). Certain qualitative information on metal bonding, based on their comparative intensities of phosphorescence is presented.The solvent mixtures used for phosphorescence studies were EP (1:1), EPA (1:2:8) and EPAF (6:5:3:0.5). The absorption spectra of both the pure solvents and the mixtures mentioned above were studied at room temperature for the purpose of characterizing the type of transition. They all showed appreciable red shifts and were then interpreted in terms ofπ‐πtriplet transi
ISSN:0009-4536
DOI:10.1002/jccs.196200025
出版商:WILEY‐VCH Verlag
年代:1962
数据来源: WILEY
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4. |
Determination of Vanadium by the Extraction of Vanadium(III) Thiocyanate with Methyl Ethyl Ketone |
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Journal of the Chinese Chemical Society,
Volume 9,
Issue 4,
1962,
Page 249-258
Tsai‐Teh Lai,
Shou‐Nan Chen,
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摘要:
AbstractThe spectrophotometric study on the extraction behavior of V(III) thiocyanate complex, with methyl ethyl ketone is described.The greenish yellow color extract shows a absorbance maximum at 395 mμ in 1.0 to 2.8NHCl solution, and the molar absorbancy index of the extract is 4,313. Beer's Law is valid over a range from 0.01mgto 0.1mgof vanadium.The optimum concentration of SnCl2for the reduction of vanadate was found at the range between 0.2Nand 0.4N.The minimum variation of the volume of organic solvent layer and aqueous layer after equilibration was found when the solution was 1.8 to 2.4Nin HCl, 0.35 to 0.65Nin SnCl2and 0.9 to 1.2Min NH4CNS
ISSN:0009-4536
DOI:10.1002/jccs.196200026
出版商:WILEY‐VCH Verlag
年代:1962
数据来源: WILEY
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5. |
Chelatometric Titration of Cobalt and Nickel with Gallein as Indicator |
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Journal of the Chinese Chemical Society,
Volume 9,
Issue 4,
1962,
Page 259-266
Peng‐Joung Sun,
Fa‐Chun Chou,
Cha‐Pying Yeh,
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摘要:
AbstractIn continuation of a series of chelatometric titration of metal ion with gallein indicator, two procedures for the EDTA titration of cobalt and nickel using gallein as indicator were proposed. In one procedure cobalt ion was titrated with standard 0.05MEDTA solution in ammonium chloride buffer by stepwise addition of ammonia to keep thepH at the optimum value of 8. A sharp color change from violet to rose red indicating the end point can be observed. In another procedure nickel ion was titrated with standard 0.05MEDTA solution atpH 8 to 9 in ammonia‐ammonium chloride buffer solution. The end point is indicated by a color change from bluish violet to rose red.The interference caused by the presence of approximately equal molar concentration of various foreign ions was observe
ISSN:0009-4536
DOI:10.1002/jccs.196200027
出版商:WILEY‐VCH Verlag
年代:1962
数据来源: WILEY
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6. |
The Chemistry of 8‐Mercaptoquinoline and its Derivatives. II. Kinetics of the Alcoholysis of S‐Benzoyl‐8‐Mercaptoquinoline |
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Journal of the Chinese Chemical Society,
Volume 9,
Issue 4,
1962,
Page 267-272
H. S. Lee,
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摘要:
AbstractThe Kinetics of the alcoholysis of S‐benzoyl‐8‐mercaptoquinoline has been investigated by using spectrophotometric m
ISSN:0009-4536
DOI:10.1002/jccs.196200028
出版商:WILEY‐VCH Verlag
年代:1962
数据来源: WILEY
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7. |
Infra‐Red Absorption Spectra of O‐Methylsilyl Derivatives of Some Alcohols andp‐Xylenol |
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Journal of the Chinese Chemical Society,
Volume 9,
Issue 4,
1962,
Page 273-279
Sheng‐Lieh Liu,
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摘要:
AbstractInfrared spectra of O‐methylsilylderivatives ofn‐pentanol, isopentanol, geraniol, citronellol, and menthol, all previously unknown, are reported. Similiar derivatives ofp‐xylenol have also been exa
ISSN:0009-4536
DOI:10.1002/jccs.196200029
出版商:WILEY‐VCH Verlag
年代:1962
数据来源: WILEY
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8. |
Mannich Bases Derived from 3‐Pipecoline, 4‐Pipecoline and 2, 6‐Dimethylmorpholine |
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Journal of the Chinese Chemical Society,
Volume 9,
Issue 4,
1962,
Page 280-289
Frank Cheng Sun,
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摘要:
Abstract3‐Methylpiperidine, 4‐methylpiperidine, and 2, 6‐dimethylmorpholine were used to condense separately with sixteen different ketones and paraformaldehyde to yield various Mannich bases. All the hydrochlorides of Mannich bases prepared in this work were tested for their solubilities in water, in 0.1Nhydrochloric acid and in 0.1Nsodium hydr
ISSN:0009-4536
DOI:10.1002/jccs.196200030
出版商:WILEY‐VCH Verlag
年代:1962
数据来源: WILEY
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9. |
Extraction of Itaconic Acid from Aqueous Solution by Ion Exchange Method |
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Journal of the Chinese Chemical Society,
Volume 9,
Issue 4,
1962,
Page 290-297
June C. Y. Tsao,
Ting‐Chia Huang,
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摘要:
AbstractThe extraction of itaconic acid from aqueous solution by the ion exchange method has been studied.With the anion exchange resin Amberlite IR‐45(OH) both ammonium hydroxide and sodium hydroxide can be used as effective elutriants and can concentrate the itaconic acid solution to three fold in a single run.Sodium hydroxide is comparatively a better elutriant than ammonium hydroxide.More concentrated elutriants (about 4NNH4OH and 3NNaOH) give sharper peaks and narrower ranges under the peaks of the elution curves and complete the elution to 96–99% at an earlier stage than the dilute o
ISSN:0009-4536
DOI:10.1002/jccs.196200031
出版商:WILEY‐VCH Verlag
年代:1962
数据来源: WILEY
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10. |
A Rapid Method for the Determination of Invert Sugar in the Presence of Large Amounts of Sucrose |
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Journal of the Chinese Chemical Society,
Volume 9,
Issue 4,
1962,
Page 298-307
Mei‐Wei Hwang,
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摘要:
AbstractA new modified Fehling's solution withpH 10.7 has been prepared for the determination of reducing sugar by means of Eynon‐Lane method in the presence of large amounts of sucrose. The amount of reducing sugar ranging from 14.4% to 0.03% in the presence of 5–20gof sucrose per 100mlcan be determined. The titre and concentration of reducing sugar relation may be expressed by the equationy=b
ISSN:0009-4536
DOI:10.1002/jccs.196200032
出版商:WILEY‐VCH Verlag
年代:1962
数据来源: WILEY
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