|
1. |
In Memoriam: Kirill llyich Zamaraev (1939-1996) |
|
Catalysis Reviews,
Volume 39,
Issue 1-2,
1997,
Page 1-4
Preview
|
PDF (339KB)
|
|
ISSN:0161-4940
DOI:10.1080/01614949708006466
出版商:Taylor & Francis Group
年代:1997
数据来源: Taylor
|
2. |
Dehydrocyclization of Alkanes Over Zeolite-Supported Metal Catalysts: Monofunctional or Bifunctional Route |
|
Catalysis Reviews,
Volume 39,
Issue 1-2,
1997,
Page 5-48
PAUL MÉRIAUDEAU,
CLAUDE NACCACHE,
Preview
|
PDF (2627KB)
|
|
摘要:
The direct catalytic conversion of alkanes into aromatics has found potentially important industrial applications. Initially only alkanes with 6 and more carbon atoms in the chain were concerned. Supported platinum catalysts were found active for the aromatization of alkanes; the drawbacks of these catalysts were their deactivation with time on stream and the existence of simultaneous parallel reactions. Much discussion has been published on the aromatization of C6+alkanes. A bifunctional mechanism which involves both the metal and the acid sites of the support and a monofunctional mechanism involving only the metallic sites operate over, respectively, Pt supported on acidic support and Pt supported on nonacidic support. In the present review the mechanisms proposed for the aromatization of alkanes are described. Over monofunctional Pt catalysts two possible mechanisms prevail: 1,6 ring closure on the Pt surface involving primary and secondary C-H bond rupture, followed by dehydrogenation of the cycloalkanes into aromatics (1,5 ring closure to a lesser extent also contributes to aromatic production); or dehydrogenation of the alkanes into olefins, dienes, and trienes followed by thermal ring closure. Zeolites were found most suitable as support for preparing catalysts more active and more selective in the alkane aromatization. In addition catalysts based on noble metals supported on zeolite appeared more resistant against deactivation by coke. In this review the aromatization of hexane, heptane, and octane over Pt-zeolite catalysts is discussed in detail. Comparisons between different zeolite structures and different dehydrogenation sites are given. In particular a critical analysis of the results and interpretation concerning Pt-KL catalysts strongly suggests that the exceptional high selectivity towards aromatization ofn-hexane exhibited by Pt-KL could not be explained by only the nest or constraint effect exerted by the channel dimension and morphology, not by only the terminal cracking properties, not by only the partial electron transfer from the zeolite support to the Pt particles, and not by only the Pt particle size. Zeolite structure also affects the aromatic product distribution, in particular when the alkane contains more than 7 carbon atoms. It is shown how Pt on medium-pore zeolites such as In-ZSM-5, silicalites will favor the aromatization of C8alkane isomers into ethylbenzene-styrene with respect to other C8aromatics. Aromatization of light alkanes, C2-C5, requires the increase of the hydrocarbon chain length up to 6 carbon atoms and higher, followed by cyclization reaction. Recently new processes to convert C2-C5alkanes into aromatics have been disclosed, M2-forming from Mobil, Cyclar from BP-UOP, and Aroforming from IFP-Saluted. In general these processes use bifunctional catalysts possessing a dehydrogenating and an acid function. The catalysts consist of a metal ion or metal oxide supported on a microporous acid solid. In this review we analyze the results concerning mainly platinum supported on pentasil-type zeolite. It is shown that althoug Pt has better dehydrogenating properties as compared with gallium and zinc, the efficiency of catalysts based on Pt-ZSM-5 for light alkane aromatization is less because undersirable reactions such as hydrogenolysis and ethene (olefins) hydrogenation occur on the platinum surface, resulting in the production of unreactive alkanes, CH2, C2H6. These drawbacks could be partially suppressed by alloying Pt and by increasing the reaction temperature.
ISSN:0161-4940
DOI:10.1080/01614949708006467
出版商:Taylor & Francis Group
年代:1997
数据来源: Taylor
|
3. |
Reproducibility of Turnover Rates in Heterogeneous Metal Catalysis: Compilation of Data and Guidelines for Data Analysis |
|
Catalysis Reviews,
Volume 39,
Issue 1-2,
1997,
Page 49-76
FABIOH. RIBEIRO*,
ALEXISE. SCHACH VON WITTENAU,
CALVINH. BARTHOLOMEW,
GABORA. SOMORJAI,
Preview
|
PDF (1576KB)
|
|
摘要:
The combination of turnover rate measurements and surface science techniques allows a firm quantification of rates in heterogeneous catalysis by metals. There are many examples of reactions where the turnover rates from different laboratories are the same. However, there are still problems, as in the isomerization and hydrogenolysis of hydrocarbons over noble metals, where the turnovers rates from different laboratories differ by many orders of magnitude. An explanation for this discrepancy is discussed. Guidelines for experimental work in heterogeneous catalysis that will help to minimize this wide scatter of turnover rates in the future are presented.
ISSN:0161-4940
DOI:10.1080/01614949708006468
出版商:Taylor & Francis Group
年代:1997
数据来源: Taylor
|
4. |
Surface Science Approach to Modeling Supported Catalysts |
|
Catalysis Reviews,
Volume 39,
Issue 1-2,
1997,
Page 77-168
PIETERL. J. GUNTER,
J.W. (HANS) NIEMANTSVERDRIET,
FABIOH. RIBEIRO,
GABORA. SOMORJAI,
Preview
|
PDF (9182KB)
|
|
摘要:
Nanoscale structural information underlies research aimed at fabricating catalysts in a more controlled way. Surface science methods can provide that information, but the complexity of heterogeneous systems in general hinders the application of these methods to their full potential. In the last decades, a solution to this problem has been found in the use of model systems, ranging from well-defined single crystals of the supported phase to films or particles of that phase on flat or spherical model supports. In this paper, we review the literature on the latter model systems, that is, particles on a model support. Attention is payed to both preparation and use of such model systems.
ISSN:0161-4940
DOI:10.1080/01614949708006469
出版商:Taylor & Francis Group
年代:1997
数据来源: Taylor
|
|