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Studies on Phosphorus-Containing Polymers. VIII. On the Reaction of Triphosphonitrilic Chloride with Cyclohexanol or Allyl Alcohol |
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Journal of Macromolecular Science: Part A - Chemistry,
Volume 18,
Issue 5,
1982,
Page 839-852
Fumiaki Yamada,
Masaaki Yokoyama,
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摘要:
Triphosphonitrilic chloride (PNCl2)3was prepared from phosphorus pentachloride with ammonium chloride. This paper is concerned with the reaction of triphosphonitrilic chloride and cyclohexanol or allyl alcohol, and with the properties of cyclohexyl or allyl triphosphonitrilic acid esters. We studied three methods: (1) reaction of triphosphonitrilic chloride with cyclohexanol or allyl alcohol by heating, (2) condensation of sodium cyclohexyl or allyl alcoholate with triphosphonitrilic chloride, (3) condensation of triphosphonitrilic chloride with cyclohexanol or allyl alcohol in the presence of pyridine as a catalyst. The result was that the synthesis of hexacyclohexyl or hexaallyl triphosphonitrilic acid esters can be accomplished by employing the second method, but the first and third methods do not work.
ISSN:0022-233X
DOI:10.1080/00222338208074438
出版商:Taylor & Francis Group
年代:1982
数据来源: Taylor
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Editorial board page for “Journal of Macromolecular Science—Chemistry”, Volume 18, Number 5 |
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Journal of Macromolecular Science: Part A - Chemistry,
Volume 18,
Issue 5,
1982,
Page -
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PDF (46KB)
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摘要:
This is a scanned image of the original Editorial Board page(s) for this issue.
ISSN:0022-233X
DOI:10.1080/00222338208074427
出版商:Taylor & Francis Group
年代:1982
数据来源: Taylor
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