1. |
Mössbauer Effect and Resistivity Studies in Fe1.11Te |
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Israel Journal of Chemistry,
Volume 9,
Issue 1,
1971,
Page 1-5
E. Hermon,
R. D. Nolan,
S. Shtrikman,
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摘要:
AbstractMössbauer effect and electrical resistivity measurements were undertaken on Fe571.11Te. The Mössbauer studies show a magnetic ordering at 68°K, which is identified with the antiferromagnetic transition previously reported for this phase. Comparison of the room and liquid helium temperature spectra indicate that the antiferromagnetic axis lies in the tetragonal plane. The temperature coefficient of the resistivity changes sign near the transition temperature and has a maximum at the transition temperatu
ISSN:0021-2148
DOI:10.1002/ijch.197100002
出版商:WILEY‐VCH Verlag
年代:1971
数据来源: WILEY
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2. |
Ultraviolet Absorption Spectrum of Toluene‐D8 |
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Israel Journal of Chemistry,
Volume 9,
Issue 1,
1971,
Page 7-14
P. C. Upadhya,
G. D. Baruah,
K. N. Upadhya,
D. K. Rai,
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摘要:
AbstractThe near ultraviolet absorption spectrum of toluene‐d8has been recorded with the help of a E1large quartz spectrograph. The (O,O) band has been identified at 37672 cm−1. The spectrum has been analysed with the help of the excited state fundamentals 282, 378, 431, 454, 508, 700, 926, 1150 and 1432 cm−1. These frequencies have been correlated with the corresponding frequencies of the normal molecule. The ration R = ν(C6H5CH3)/ν(C6D5CD3) has been calculated for each excited state mode of vibration and compared with the corresponding value of R found for the ground state vib
ISSN:0021-2148
DOI:10.1002/ijch.197100003
出版商:WILEY‐VCH Verlag
年代:1971
数据来源: WILEY
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3. |
Determination of Chloride Content in Compounds and in Solutions of High Bromide to Chloride Concentration Ratios |
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Israel Journal of Chemistry,
Volume 9,
Issue 1,
1971,
Page 15-24
Y. Israel,
L. Gonen,
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摘要:
AbstractA method is described for the determination of chloride in compounds and in solutions of high bromide to chloride molar ratios (up to 6300:1). Solutions were boiled briefly with nitric acid to oxidize the bulk concentration of bromide ion to bromine gas which was then flushed with air. Chloride ion was titrated potentiometrically with silver nitrate in 80% i‐propanol‐water medium using a silver‐silver bromide indicator electrode and a chloride‐free reference electrode. Details of the potentiometric techniques peculiar to these titrations are described. The method was successfully applied to the determination of the chloride content of commercially available bromide r
ISSN:0021-2148
DOI:10.1002/ijch.197100004
出版商:WILEY‐VCH Verlag
年代:1971
数据来源: WILEY
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4. |
Nephelometric Measurements by Use of a Spectrofluorometer. Part I: (A) Determination of Sulphate; and (B) Determination of Calcium |
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Israel Journal of Chemistry,
Volume 9,
Issue 1,
1971,
Page 25-33
L. Gonen,
E. Cogan,
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摘要:
AbstractAn approach to quantitative nephelometric measurements using a spectrofluorometer is presented. The measurements are performed with the aid of a monochromatic filter, which is transparent for the line 546 nm and by adjusting the monochromator for the same wavelength. The method was applied for the determination of micro amounts of: (1) sulphate as barium sulphate in colorless or colored aqueous solutions, in phosphoric acid, in the presence of large amounts of iron and in ores; is also suitable for determination of total inorganic sulfur after oxidation to sulphate and in organics after combustion; (2) calcium as calcium naphthalhydroxamate in aqueous and phosphoric acid solutions; and (3) calcium in the presence of large amounts of magnesium. The proposed technique has proved useful for quantitative nephelometric determinations in colored solutions. The high sensitivity also permits the use of micro samples.
ISSN:0021-2148
DOI:10.1002/ijch.197100005
出版商:WILEY‐VCH Verlag
年代:1971
数据来源: WILEY
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5. |
Reactions of Dimethyl Benzoylphosphonate |
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Israel Journal of Chemistry,
Volume 9,
Issue 1,
1971,
Page 35-44
I. Shahak,
J. Peretz,
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摘要:
AbstractReactions of dimethyl benzoylphosphonate (I) with various nucleophiles are described. The ester can serve simply as a useful benzoylation agent or it can undergo addition reactions to give substituted α‐hydroxybenzylphosphonates. Its keto‐group can be reduced to hydroxyl and can participate in the Wittig‐Horner reaction. By the action of I with hydroxylamine in the presence of sodium formate, benzonitrile is ob
ISSN:0021-2148
DOI:10.1002/ijch.197100006
出版商:WILEY‐VCH Verlag
年代:1971
数据来源: WILEY
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6. |
The Effect of Buffered Sodium Dithionite Solution and Ultrasonic Agitation on Soil Clays |
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Israel Journal of Chemistry,
Volume 9,
Issue 1,
1971,
Page 45-52
B. D. Mitchell,
B. F. L. Smith,
A. S. De Endredy,
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摘要:
AbstractA rapid method for removing free ferric oxides from soil clays with sodium dithionite solution buffered with sodium bicarbonate solution is described. Effective dispersion of the clay suspension during this extraction procedure is achieved by means of ultrasonic agitation. Methods are proposed for the determination of silica and alumina in the dithionite extract which are more reliable than those previously employed. Kaolinite and micaceous clay minerals are unaffected by the treatment but certain chloritic minerals appear to be susceptible to attack.
ISSN:0021-2148
DOI:10.1002/ijch.197100007
出版商:WILEY‐VCH Verlag
年代:1971
数据来源: WILEY
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7. |
Reactions of ReF7and ReOF5with Fluoride Ion Donors |
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Israel Journal of Chemistry,
Volume 9,
Issue 1,
1971,
Page 53-56
H. Selig,
Z. Karpas,
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摘要:
AbstractReactions of ReF7and ReOF5with NOF and NO2F yielded the compounds NO+ReF8−, NO2+ReF8−, NO+ReOF6−and NO2+ReOF6−. Raman spectra of the solids and NMR spectra of solutions in anhydrous HF show that the complexes are ionic and give tentative indications that ReF8−has D4dsymmetry and ReOF6−has
ISSN:0021-2148
DOI:10.1002/ijch.197100008
出版商:WILEY‐VCH Verlag
年代:1971
数据来源: WILEY
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8. |
Spiranic β‐Ketoesters and their Pyrazolinones |
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Israel Journal of Chemistry,
Volume 9,
Issue 1,
1971,
Page 57-61
R. Breiman,
M. Avramoff,
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摘要:
AbstractA number of spiranic β‐ketoesters have been prepared and transformed into the corresponding phenylpyrazolinones by condensation with phenylhydrazine. The structures of the β‐ketoesters and the pyrazolinones, derived from their UV, IR and NMR spectra, are disc
ISSN:0021-2148
DOI:10.1002/ijch.197100009
出版商:WILEY‐VCH Verlag
年代:1971
数据来源: WILEY
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9. |
Base Induced Isomerization of γ, δ‐Epoxyketones |
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Israel Journal of Chemistry,
Volume 9,
Issue 1,
1971,
Page 63-69
Y. Gaoni,
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摘要:
AbstractBase treatment of open‐chain γ, δ ‐ epoxyketones yields usually two cyclopropane derivatives, a trans‐1‐acy1‐2(α ‐ hydroxyalkyl) cyclopropane (II) and a 2‐hydroxy‐3‐oxabicyclo[3, 1, 0] hexane (III). The NMR spectra and some other physical properties of compounds II and III and of some of their transformation p
ISSN:0021-2148
DOI:10.1002/ijch.197100010
出版商:WILEY‐VCH Verlag
年代:1971
数据来源: WILEY
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10. |
Inductive Effects on Molecular Ionization Potentials. III.Primary, Secondary and Tertiary Aliphatic Amines |
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Israel Journal of Chemistry,
Volume 9,
Issue 1,
1971,
Page 71-73
Barbara W. Levitt,
L. S. Levitt,
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摘要:
AbstractIt is demonstrated that the ionization potentials of primary, secondary, and tertiary aliphatic amines correlate very well with the inductive and polar substituent constants, the only seriously deviating value being that for ammonia, itself. The correlation equation is found to be EI= 9.62 + 13.8 Σσ
ISSN:0021-2148
DOI:10.1002/ijch.197100011
出版商:WILEY‐VCH Verlag
年代:1971
数据来源: WILEY
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