1. |
Abstracts |
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Journal of Applied Chemistry,
Volume 8,
Issue 1,
1958,
Page 1-112
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ISSN:0021-8871
DOI:10.1002/jctb.5010080113
出版商:John Wiley&Sons, Ltd
年代:1958
数据来源: WILEY
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2. |
Gas‐liquid chromatography. I. Retention‐volume data of certain tar acids |
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Journal of Applied Chemistry,
Volume 8,
Issue 1,
1958,
Page 3-6
L. Irvine,
T. J. Mitchell,
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摘要:
AbstractThe corrected retention volumes per gram of stationary phase (Vg) are given for thirty tar acids at 183°, 155° and 135°. The results were obtained from a 4‐ft. column using Apiezon‐L stopcock grease as stationary phase and Celite‐535 as mechanical support. The carrier gas was nitrogen and thermal conductivity was used for detection of cons
ISSN:0021-8871
DOI:10.1002/jctb.5010080102
出版商:John Wiley&Sons, Ltd
年代:1958
数据来源: WILEY
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3. |
Investigations into the electrodeposition of titanium metal from titanium tetrachloride in fused alkali metal chloride systems |
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Journal of Applied Chemistry,
Volume 8,
Issue 1,
1958,
Page 6-13
J. Burgess,
G. T. Brown,
C. W. Roberts,
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摘要:
AbstractAn account is presented of work carried out on the single‐stage, electrolytic reduction of TiCl4to titanium metal. Emphasis is placed on metal quality as determined by hardness values, and the effects of a number of experimental variables have been studied both on hardness and on current efficiency and yield. In several cases, a minimum hardness level of 300–350 D.P.N. on melted metal was achieved, and it was shown to be possible to prepare titanium metal of this quality at high current efficiency and yield. The use of porous diaphragms in the cell, whilst necessary for high efficiencies, resulted in an irregular contamination of the metal throughout any one experiment, although not affecting the minimum hardness obtained. The deposited metal was, in all cases, of small particle size and generally dendritic in struct
ISSN:0021-8871
DOI:10.1002/jctb.5010080103
出版商:John Wiley&Sons, Ltd
年代:1958
数据来源: WILEY
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4. |
A filtration and vacuum distillation unit for the purification of alkali metals |
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Journal of Applied Chemistry,
Volume 8,
Issue 1,
1958,
Page 13-18
G. W. Horsley,
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摘要:
AbstractA combined filtration and vacuum distillation apparatus for producing high‐purity alkali metals is described. Operating data for the preparation of distilled lithium, sodium and potassium are give
ISSN:0021-8871
DOI:10.1002/jctb.5010080104
出版商:John Wiley&Sons, Ltd
年代:1958
数据来源: WILEY
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5. |
The relationship between magnesium content and stress‐corrosion susceptibility of aluminium‐magnesium alloys |
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Journal of Applied Chemistry,
Volume 8,
Issue 1,
1958,
Page 18-23
W. J. Vance,
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摘要:
AbstractThe susceptibility to stress‐corrosion cracking of commercial purity aluminium‐3.5% magnesium and aluminium‐2.25% magnesium (nominal) alloys has been determined by corroding strain‐aged 16 s.w.g. wire specimens by intermittent immersion in buffered 3% sodium chloride solution. Susceptibility values for the 3.5%‐Mg and 2.25%‐Mg alloys were 18.4% and 0% respectively.Comparison with the stress‐corrosion susceptibility values reported by Jones1on aluminium‐7% magnesium and aluminium‐5% magnesium alloys suggests that susceptibility is proportional to alloying magnesium content within the range of alloys examin
ISSN:0021-8871
DOI:10.1002/jctb.5010080105
出版商:John Wiley&Sons, Ltd
年代:1958
数据来源: WILEY
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6. |
The surveillance of cinematograph record film during storage |
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Journal of Applied Chemistry,
Volume 8,
Issue 1,
1958,
Page 24-34
G. L. Hutchison,
L. Ellis,
S. A. Ashmore,
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摘要:
AbstractA number of cellulose nitrate‐base cinematograph films have been examined, many of which are twenty or thirty years old. Reactions between decomposition products of the base and gelatin had in some cases caused the emulsion layer to become sticky with loss of the contained silver image. Since films in this condition cannot be duplicated, it represents a total loss of record. This can now be avoided by subjecting the film to certain tests, the results of which give adequate warning of the onset of the critical stage, thereby enabling the film to be duplicated while still in good physical and optical condition. The application of these tests has been incorporated in a scheme of surveillance devised for use with stored fil
ISSN:0021-8871
DOI:10.1002/jctb.5010080106
出版商:John Wiley&Sons, Ltd
年代:1958
数据来源: WILEY
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7. |
The formation of metastable aluminas at high temperatures |
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Journal of Applied Chemistry,
Volume 8,
Issue 1,
1958,
Page 35-44
M. Plummer,
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摘要:
AbstractThe formation of metastable alumina by the rapid cooling of droplets of molten alumina is described. The necessary conditions are discussed and a possible mechanism is suggested. Some consideration is given to the effect of impurities.
ISSN:0021-8871
DOI:10.1002/jctb.5010080107
出版商:John Wiley&Sons, Ltd
年代:1958
数据来源: WILEY
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8. |
The preparation of crystalline δ‐alumina |
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Journal of Applied Chemistry,
Volume 8,
Issue 1,
1958,
Page 44-49
H. P. Rooksby,
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摘要:
AbstractThree methods are described for preparing une of the transition forms of alurtlina, the δ‐fornt, in a comparatively advanced state of crystallinity. In these preparations the crystal structure is sufficiently well‐developed for complete X‐ray powder diffraction spacing and intensity data to be compiled, and these data are presented. The methods of preparation comprise:(a)Heat treatment of a dense form of high‐purity alumina monohydrate in air at about 950° over an extended period.(a)Ignition of ammonium aluminium sulphate impregnated with ammonium molybdate at 950°.(a)Heat treatment at 1100° in air of a flame‐sprayed alumina displaying the cubic gamma structure.The spherulized alumina described by Plumnier in the preceding paper contains a high proportion of cryst
ISSN:0021-8871
DOI:10.1002/jctb.5010080108
出版商:John Wiley&Sons, Ltd
年代:1958
数据来源: WILEY
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9. |
Electrodialysis using ion‐exchange membranes. I. Factors limiting the degree of desalting |
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Journal of Applied Chemistry,
Volume 8,
Issue 1,
1958,
Page 49-59
S. M. Partridge,
A. M. Peers,
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摘要:
AbstractThe behaviour of potassium chloride solutions in a continuously operated electrodialysis cell using ion‐exchange membranes is described. The cell contained 25 desalting compartments and 25 concentrating compartments each 1.58 mm. thick. The membranes were supported by perforated separators carrying grooves for the passage of liquid, and turbulent flow was induced by forced recirculation. The dependence of current efficiency on the ion concentration in the desalting compartments was assessed and the effect of a number of design factors was investigated. Theoretical expressions have been derived for the current efficiency of the desalting proces
ISSN:0021-8871
DOI:10.1002/jctb.5010080109
出版商:John Wiley&Sons, Ltd
年代:1958
数据来源: WILEY
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10. |
Electrodialysis using ion‐exchange membranes II.Demineralization of solutions containing amino‐acids |
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Journal of Applied Chemistry,
Volume 8,
Issue 1,
1958,
Page 59-67
A. M. Peers,
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摘要:
AbstractWhen the ratio of electrical transport numbers (ratio of fluxes) of two ionic species in a membrane has a value different from the ratio of concentrations in free solution, the membrane may be utilized to effect a partial separation of the two species. The degree of separation may be characterized by a ‘separation factor’, a, which has been evaluated theoretically for a simple case. The effect of current density on a is also considered. The theory is utilized to determine the optimum conditions for the separation of amino‐acids from sodium chloride in a three‐compartment cell employing ion‐exchange membranes. Results are in general agreement wi
ISSN:0021-8871
DOI:10.1002/jctb.5010080110
出版商:John Wiley&Sons, Ltd
年代:1958
数据来源: WILEY
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