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Enantiomer Separation of n-1-Alkenyl-3-Acetates and of Alkyl Substituted 1,3-Dioxolanes by Complexation Gas Chromatography

 

作者: V. Schurig,   H. Laderer,   D. Wistuba,   A. Mosandl,   V. Schubert,   U. Hagenauer-Hener,  

 

期刊: Journal of Essential Oil Research  （Taylor Available online 1989）
卷期: Volume 1, issue 5  

页码: 209-221

 

ISSN:1041-2905

 

年代: 1989

 

DOI:10.1080/10412905.1989.9697788

 

出版商: Taylor & Francis Group

 

关键词: Enantiomeric separation;complexation gas chromatography;Nickel(11)bis-[3-(heptafluorobutanoyl)-(1R)-camphorate];1-alkenyl-3-acetates;2-methyl-l-butyl acetate;2,2,4-trimethyl-5-sec-butyl-1,3-dioxolane;2-sec-butyl-4-methyl-1,3-dioxolane

 

数据来源: Taylor

 

摘要:

The simultaneous enantiomer separation of a homologous series of n-1-alkenyl-3-acetates on nickel(II)bis[3-(heptafluorobutanoyl)-(1R)-camphorate] and of alkyl-substituted 1,3-dioxolanes containing three chiral centers on nickel(II)bis[3-(heptafluorobutanoyl)-(1R)-camphorate] and on nickel(II)bis[3-(heptafiuorobutanoyl)-(1R,2S)-pinan-4-onate] by complexation gas chromatography is described. The method allows the rapid screening of the stereochemistry of the title compounds in biological mixtures.

 

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