Ordering process of lamellar microdomains following morphological transition from cylindrical microdomains in block copolymer melts
作者:
Shinichi Sakurai,
Kazuhiro Taie,
Toshikazu Momii,
Shunji Nomura,
期刊:
AIP Conference Proceedings
(AIP Available online 1992)
卷期:
Volume 256,
issue 1
页码: 234-235
ISSN:0094-243X
年代: 1992
DOI:10.1063/1.42354
出版商: AIP
数据来源: AIP
摘要:
Ordering process of lamellar microdomains of poly(styrene‐block‐butadiene‐block‐styrene) (SBS) triblock copolymers in melts has been studied using small‐angle X‐ray scattering (SAXS). The SAXS profiles were analyzed by means of the theoretical calculation based on the one‐dimensional paracrystal model so as to characterize quantitatively how the lamellae which were formed through coalescence of cylindrical microdomains ordered. As a result of the analysis, it was found that the distribution of the interlamellar distance and the thickness distributions of polystyre (PS) and polybutadiene (PB) lamellae decreased, whereas the interlamellar distance and the interfacial thickness did not definitely change with time.
点击下载:
PDF
(165KB)
返 回